Technology Process of cis,cis-1,3,5-trisformylcyclohexane
There total 8 articles about cis,cis-1,3,5-trisformylcyclohexane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
oxalyl dichloride; dimethyl sulfoxide;
In
dichloromethane;
at -55 ℃;
for 2.25h;
DOI:10.1021/jo00385a002
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 97 percent / HCl )g) / 1 h / Heating
2: 98 percent / acetic acid, hydrogen / platinum oxide / 3.5 h / 25 °C / 1034.3 - 2585.7 Torr
3: 83.7 percent / lithium aluminum hydride / tetrahydrofuran / 16 h / Heating
4: 70 percent / dimethyl sulfoxide, oxalyl chloride / CH2Cl2 / 2.25 h / -55 °C
With
hydrogenchloride; lithium aluminium tetrahydride; oxalyl dichloride; hydrogen; acetic acid; dimethyl sulfoxide;
platinum(IV) oxide;
In
tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00385a002
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 99.5 percent / H2, acetic acid / platinum oxide / 3.5 h / 25 °C / 1034.3 - 2585.7 Torr
2: 81 percent / lithium aluminum hydride / diethyl ether / 16 h / Heating
3: 70 percent / dimethyl sulfoxide, oxalyl chloride / CH2Cl2 / 2.25 h / -55 °C
With
lithium aluminium tetrahydride; oxalyl dichloride; hydrogen; acetic acid; dimethyl sulfoxide;
platinum(IV) oxide;
In
diethyl ether; dichloromethane;
DOI:10.1021/jo00385a002
