1-BROMO-8-PHENYLOCTANE

Base Information

• Chemical Name: 1-BROMO-8-PHENYLOCTANE
• CAS No.: 54646-75-2
• Molecular Formula: C14H21Br
• Molecular Weight: 269.225
• Hs Code.: 2903999090
• Mol file: 54646-75-2.mol

Synonyms:Octane,1-bromo-8-phenyl- (6CI);(8-Bromooctyl)benzene;1-Bromo-8-phenyloctane;8-Phenyloctyl bromide;

Chemical Property of 1-BROMO-8-PHENYLOCTANE

Chemical Property:

• Vapor Pressure: 0.000302mmHg at 25°C
• Refractive Index: 1.52
• Boiling Point: 331.3 °C at 760 mmHg
• Flash Point: 171.8 °C
• PSA: 0.00000
• Density: 1.148g/cm³
• LogP: 4.96460

Purity/Quality:

98%min ^*data from raw suppliers

1-Bromo-8-phenyloctane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-BROMO-8-PHENYLOCTANE

There total 14 articles about 1-BROMO-8-PHENYLOCTANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

8-phenyloctan-1-ol (10472-97-6) → 1-bromo-8-phenyloctane (54646-75-2)

Guidance literature:

With carbon tetrabromide; triphenylphosphine; In dichloromethane; at 0 ℃; for 1h;

DOI:10.1021/jm00147a004

Reference yield: 75.0%

1,8-dibromooctane (4549-32-0) + phenyllithium (591-51-5) → 1-bromo-8-phenyloctane (54646-75-2)

Guidance literature:

In tetrahydrofuran; diethyl ether; hexane; at -14 - 20 ℃; for 7h; Inert atmosphere;

DOI:10.1002/anie.201101821

Reference yield: 61.0%

1,8-dibromooctane (4549-32-0) + phenylmagnesium bromide (100-58-3) → 1-bromo-8-phenyloctane (54646-75-2)

Guidance literature:

With dilithium tetrachlorocuprate; In tetrahydrofuran; for 20h; Ambient temperature;

DOI:10.1016/S0223-5234(99)80029-4

upstream raw materials:

8-phenyloctan-1-ol

Acetic acid 8-phenyl-octyl ester

1,8-dibromooctane

phenylmagnesium bromide

Downstream raw materials:

1-Phenyl-8-<4-amino-2-methoxy-phenoxy>-octan

N,N-dimethyl-8-phenyloctylamine

Refernces

• 1、 Bajzíková, Kvetoslava,Svoboda, Ji?í,Novotná, Vladimíra,Pociecha, Damian,Gorecka, Ewa. "Bent-core mesogens with an aromatic unit at the terminal position". supporting information. p. 4672 - 4679. Retrieved 2017/07/10.
• 2、 Tiedemann, Bryan E. F.,Raymond, Kenneth N.. "Dangling arms: A tetrahedral supramolecular host with partially encapsulated guests". . p. 83 - 86. Retrieved 2007/10/03.