trans-(bis{[2,5-dimethoxy-4-(2-{4-[2-(4-{[(triisopropylsilyl)oxy]methyl}phenyl)ethynyl]-phenyl}ethynyl)phenyl]ethyne}bis(tri-n-butylphosphine))platinum

Base Information

• Chemical Name: trans-(bis{[2,5-dimethoxy-4-(2-{4-[2-(4-{[(triisopropylsilyl)oxy]methyl}phenyl)ethynyl]-phenyl}ethynyl)phenyl]ethyne}bis(tri-n-butylphosphine))platinum
• CAS No.: 1429466-22-7
• Molecular Formula: C₉₆H₁₃₂O₆P₂PtSi₂
• Molecular Weight: 1695.3
• Mol file: 1429466-22-7.mol

Synonyms:trans-(bis{[2,5-dimethoxy-4-(2-{4-[2-(4-{[(triisopropylsilyl)oxy]methyl}phenyl)ethynyl]-phenyl}ethynyl)phenyl]ethyne}bis(tri-n-butylphosphine))platinum

Chemical Property of trans-(bis{[2,5-dimethoxy-4-(2-{4-[2-(4-{[(triisopropylsilyl)oxy]methyl}phenyl)ethynyl]-phenyl}ethynyl)phenyl]ethyne}bis(tri-n-butylphosphine))platinum

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-(bis{[2,5-dimethoxy-4-(2-{4-[2-(4-{[(triisopropylsilyl)oxy]methyl}phenyl)ethynyl]-phenyl}ethynyl)phenyl]ethyne}bis(tri-n-butylphosphine))platinum

There total 1 articles about trans-(bis{[2,5-dimethoxy-4-(2-{4-[2-(4-{[(triisopropylsilyl)oxy]methyl}phenyl)ethynyl]-phenyl}ethynyl)phenyl]ethyne}bis(tri-n-butylphosphine))platinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

trans-dichloro-bis(tri-n-butylphosphine)platinum(II) (15391-01-2,15076-72-9,15390-92-8) + {[4-(2-{4-[2-(4-ethynyl-2,5-dimethoxyphenyl)ethynyl]phenyl}ethynyl)phenyl]methoxy}triisopropylsilane (1429466-21-6) → trans-(bis{[2,5-dimethoxy-4-(2-{4-[2-(4-{[(triisopropylsilyl)oxy]methyl}phenyl)ethynyl]-phenyl}ethynyl)phenyl]ethyne}bis(tri-n-butylphosphine))platinum (1429466-22-7)

Guidance literature:

With copper(l) iodide; triethylamine; In tetrahydrofuran; at 65 ℃; for 0.1h; Microwave irradiation;

DOI:10.1016/j.tetlet.2013.02.105

Reference yield: 96.0%

trans-(bis{[2,5-dimethoxy-4-(2-{4-[2-(4-{[(triisopropylsilyl)oxy]methyl}phenyl)ethynyl]-phenyl}ethynyl)phenyl]ethyne}bis(tri-n-butylphosphine))platinum (1429466-22-7) → trans-(bis{[2,5-dimethoxy-4-(2-{4-[2-(4-{[(triisopropylsilyl)oxy]methyl}phenyl)ethynyl]phenyl}ethynyl)phenyl]ethyne}bis(tri-n-butylphosphine))platinum (1429466-10-3)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 0.5h;

DOI:10.1016/j.tetlet.2013.02.105

upstream raw materials:

trans-dichloro-bis(tri-n-butylphosphine)platinum(II)

{[4-(2-{4-[2-(4-ethynyl-2,5-dimethoxyphenyl)ethynyl]phenyl}ethynyl)phenyl]methoxy}triisopropylsilane

Downstream raw materials:

trans-(bis{[2,5-dimethoxy-4-(2-{4-[2-(4-{[(triisopropylsilyl)oxy]methyl}phenyl)ethynyl]phenyl}ethynyl)phenyl]ethyne}bis(tri-n-butylphosphine))platinum