1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-D-gulo-heptitol-1-C-yl]-2,3-dideoxy-β-D-lyxo-hexopyranose

Base Information

Chemical Name:1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-D-gulo-heptitol-1-C-yl]-2,3-dideoxy-β-D-lyxo-hexopyranose
CAS No.:556054-10-5
Molecular Formula:C₄₁H₄₆O₉
Molecular Weight:682.811
Hs Code.:

Synonyms:1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-D-gulo-heptitol-1-C-yl]-2,3-dideoxy-β-D-lyxo-hexopyranose

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Chemical Property of 1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-D-gulo-heptitol-1-C-yl]-2,3-dideoxy-β-D-lyxo-hexopyranose

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Technology Process of 1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-D-gulo-heptitol-1-C-yl]-2,3-dideoxy-β-D-lyxo-hexopyranose

There total 3 articles about 1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-D-gulo-heptitol-1-C-yl]-2,3-dideoxy-β-D-lyxo-hexopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 556054-09-2
1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-D-gulo-heptitol-1-C-yl]-2,3-dideoxy-2-(phenylthio)-β-D-galactopyranose

: 556054-10-5
1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-D-gulo-heptitol-1-C-yl]-2,3-dideoxy-β-D-lyxo-hexopyranose

Guidance literature:: nickel; In tetrahydrofuran; at 20 ℃; for 4h;
DOI:10.1002/hlca.200390037

Reference yield:

: 270923-04-1
1,6-anhydro-3-C-[(1S)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-D-gulo-heptitol-1-C-yl]-2,3-dideoxy-β-D-glycero-hex-2-en-4-ulopyranose

: 556054-10-5
1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-D-gulo-heptitol-1-C-yl]-2,3-dideoxy-β-D-lyxo-hexopyranose

Guidance literature:: Multi-step reaction with 3 steps

1: Et₃N / CH₂Cl₂ / 1.5 h / 0 °C

2: 574 mg / NaBH₄ / methanol; CH₂Cl₂ / 2 h / 0 °C

3: 85 percent / Raney-Ni / tetrahydrofuran / 4 h / 20 °C

With sodium tetrahydroborate; triethylamine; nickel; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1002/hlca.200390037

Reference yield:

: (1R,3S,4R,5R)-3-[(R)-Hydroxy-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-methyl]-4-phenylsulfanyl-6,8-dioxa-bicyclo[3.2.1]octan-2-one

: 556054-10-5
1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-D-gulo-heptitol-1-C-yl]-2,3-dideoxy-β-D-lyxo-hexopyranose

Guidance literature:: Multi-step reaction with 2 steps

1: 574 mg / NaBH₄ / methanol; CH₂Cl₂ / 2 h / 0 °C

2: 85 percent / Raney-Ni / tetrahydrofuran / 4 h / 20 °C

With sodium tetrahydroborate; nickel; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1002/hlca.200390037