cis-Cp*ZrMe(μOCH2Ph2P)2

Base Information

• Chemical Name: cis-Cp*ZrMe(μOCH2Ph2P)2
• CAS No.: 113646-88-1
• Molecular Formula: C₃₉H₄₈O₂P₂PtZr
• Molecular Weight: 897.06

Synonyms:cis-Cp*ZrMe(μOCH2Ph2P)2

Chemical Property of cis-Cp*ZrMe(μOCH2Ph2P)2

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Technology Process of cis-Cp*ZrMe(μOCH2Ph2P)2

There total 1 articles about cis-Cp*ZrMe(μOCH2Ph2P)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

cis-PtMe2(PPh2CH2OH)2 (113646-80-3) + Cp(*)ZrMe3 → cis-Cp*ZrMe(μOCH2Ph2P)2 (113646-88-1)

Guidance literature:

In toluene; adding toluene to cis-PtMe2(PPh2CH2OH)2 and Cp*ZrMe3 at -196°C, warming to -78°C, gas evolution, stirring 10 min, warming to 25°C, stirring for 48 h, reducing vol. of soln., adding hexane, pptn.; filtering, washing (hexane), drying (vacuum); elem. anal.;

DOI:10.1021/ja00221a024

Reference yield: 69.0%

cis-Cp*ZrMe(μOCH2Ph2P)2 (113646-88-1) → Cp*ZrI(μ-OCH2Ph2P)2PtMe2 (113646-86-9)

Guidance literature:

With methyl iodide; In benzene; condensing methyl iodide to cis-Cp*ZrMe(μOCH2Ph2P)2PtMe2 in benzene at -196°C, heating (92°C, 10 h); reducing vol., adding hexane, pptn., triturating with hexane, filtration, washing (hexane), drying in vacuo; 1H NMR spectrum, 31P (1H) NMR spectrum;

DOI:10.1021/ja00221a024

Reference yield:

cis-Cp*ZrMe(μOCH2Ph2P)2 (113646-88-1) + (C5(CH3)5)Zr(CD3)(OCH2CH2(C6H5)2P)2Pt(CH3)2 → cis-Cp*ZrMe(μ-OCH2CH2Ph2P)2 (113646-87-0) + (C5(CH3)5)Zr(CD3)(OCH2(C6H5)2P)2Pt(CH3)2 (113646-89-2)

Guidance literature:

In benzene-d6; 1H NMR; Kinetics;

DOI:10.1021/ja00221a024

upstream raw materials:

cis-PtMe₂(PPh₂CH₂OH)2

Downstream raw materials:

Cp*ZrI(μ-OCH2Ph2P)2PtMe2

cis-Cp*ZrMe(μ-OCH2CH2Ph2P)2

(C₅(CH₃)5)Zr(CD₃)(OCH₂(C₆H₅)2P)2Pt(CH₃)2

(C₅(CH₃)5)Zr(CH₃)(OCH₂(C₆H₅)2P)2Pt(CH₃)(CD₃)

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