[Fe(η5-C5H4-4-(C6H2(CH2NMe2)2-2,6)-1-I)2]

Base Information

• Chemical Name: [Fe(η5-C5H4-4-(C6H2(CH2NMe2)2-2,6)-1-I)2]
• CAS No.: 912482-69-0
• Molecular Formula: C₃₄H₄₄FeI₂N₄
• Molecular Weight: 818.406
• Mol file: 912482-69-0.mol

Synonyms:[Fe(η5-C5H4-4-(C6H2(CH2NMe2)2-2,6)-1-I)2]

Chemical Property of [Fe(η5-C5H4-4-(C6H2(CH2NMe2)2-2,6)-1-I)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe(η5-C5H4-4-(C6H2(CH2NMe2)2-2,6)-1-I)2]

There total 1 articles about [Fe(η5-C5H4-4-(C6H2(CH2NMe2)2-2,6)-1-I)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

[Fe(η5-C5H4-4-(C6H3(CH2NMe2)2-2,6))2] (640298-72-2) + iodine (7553-56-2,12190-71-5,8031-47-8) → [Fe(η5-C5H4-4-(C6H2(CH2NMe2)2-2,6)-1-I)2] (912482-69-0)

Guidance literature:

With n-BuLi; In diethyl ether; hexane; (N2); Schlenk technique; soln. of BuLi (2 equiv.)/hexane added to soln. of Fe complex/C6H14 at 25°C; stirred for 16 h at 25°C; volatiles removed (vac.); dissolved in Et2O; I2 added at 0°C; stirred upon warming to 25°C for 8 h; quenched with aq. Na2S2O3; org. phase septd.; extd. (H2O); dried (MgSO4); filtered; evapd. (vac.); elem. anal.;

DOI:10.1016/j.jorganchem.2006.05.052

Reference yield: 56.0%

[Fe(η5-C5H4-4-(C6H2(CH2NMe2)2-2,6)-1-I)2] (912482-69-0) + [Pt(4-tolyl)2(SEt2)]2 → [Fe(η5-C5H4-4-(C6H2(CH2NMe2)2-2,6)-1-PtI)2]*2(toluene)

Guidance literature:

In toluene; (N2); Schlenk technique; soln. of Fe complex (1 equiv.) and Pt complex (1 equiv.) in toluene was refluxed for 5 min; cooled to 25°C; filtered through Celite; concd. (vac.); hexane added; filtered; washed (hexane, Et2O); dried (vac.); elem. anal.;

DOI:10.1016/j.jorganchem.2006.05.052

upstream raw materials:

[Fe(η5-C5H4-4-(C6H3(CH2NMe2)2-2,6))2]

iodine

Refernces

• 1、 K?cher, Stefan,Walfort, Bernhard,van Klink, Gerard P.M.,van Koten, Gerard,Lang, Heinrich. "Trimetallic FePd2 and FePt2 4-ferrocenyl-NCN pincer complexes". . p. 3955 - 3961. Retrieved 2007/10/03.