Technology Process of benzoic acid 8-oxabicyclo[3.2.1]oct-3-en-2-yl ester
There total 6 articles about benzoic acid 8-oxabicyclo[3.2.1]oct-3-en-2-yl ester which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
dmap; triethylamine;
In
dichloromethane;
at 0 - 20 ℃;
for 0.5h;
Inert atmosphere;
DOI:10.1021/ol201273b
- Guidance literature:
-
Multi-step reaction with 3 steps
1: [hydroxy(tosyloxy)iodo]benzene; sodium acetate / acetonitrile / 1.5 h / 0 °C / Inert atmosphere
2: sodium tetrahydroborate / methanol / 0.17 h / -50 °C / Inert atmosphere
3: dmap; triethylamine / dichloromethane / 0.5 h / 0 - 20 °C / Inert atmosphere
With
dmap; sodium tetrahydroborate; [hydroxy(tosyloxy)iodo]benzene; sodium acetate; triethylamine;
In
methanol; dichloromethane; acetonitrile;
DOI:10.1021/ol201273b
- Guidance literature:
-
Multi-step reaction with 5 steps
1: oxygen; 5,15,10,20-tetraphenylporphyrin / dichloromethane / 60 h / 0 °C / Photolysis; Inert atmosphere
2: deMeQDAc / dichloromethane / 20 °C / Inert atmosphere
3: [hydroxy(tosyloxy)iodo]benzene; sodium acetate / acetonitrile / 1.5 h / 0 °C / Inert atmosphere
4: sodium tetrahydroborate / methanol / 0.17 h / -50 °C / Inert atmosphere
5: dmap; triethylamine / dichloromethane / 0.5 h / 0 - 20 °C / Inert atmosphere
With
deMeQDAc; dmap; sodium tetrahydroborate; [hydroxy(tosyloxy)iodo]benzene; oxygen; sodium acetate; 5,15,10,20-tetraphenylporphyrin; triethylamine;
In
methanol; dichloromethane; acetonitrile;
2: Kornblum-DeLaMare rearrangement;
DOI:10.1021/ol201273b
