S-(2-methoxycarbonyl)phenyl [(3,3-diphenyl-prop-2-enyl)oxy]thioacetate

Base Information

• Chemical Name: S-(2-methoxycarbonyl)phenyl [(3,3-diphenyl-prop-2-enyl)oxy]thioacetate
• CAS No.: 339314-70-4
• Molecular Formula: C₂₅H₂₂O₄S
• Molecular Weight: 418.513
• Mol file: 339314-70-4.mol

Synonyms:S-(2-methoxycarbonyl)phenyl [(3,3-diphenyl-prop-2-enyl)oxy]thioacetate

Chemical Property of S-(2-methoxycarbonyl)phenyl [(3,3-diphenyl-prop-2-enyl)oxy]thioacetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of S-(2-methoxycarbonyl)phenyl [(3,3-diphenyl-prop-2-enyl)oxy]thioacetate

There total 2 articles about S-(2-methoxycarbonyl)phenyl [(3,3-diphenyl-prop-2-enyl)oxy]thioacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

(3,3-diphenyl-allyloxy)-acetic acid + Methyl thiosalicylate (4892-02-8) → S-(2-methoxycarbonyl)phenyl [(3,3-diphenyl-prop-2-enyl)oxy]thioacetate (339314-70-4)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 2h;

DOI:10.1021/jo001578u

Reference yield:

benzophenone (119-61-9) → S-(2-methoxycarbonyl)phenyl [(3,3-diphenyl-prop-2-enyl)oxy]thioacetate (339314-70-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: NaH / dimethylsulfoxide / 65 °C

1.2: 20 °C

2.1: 40 percent / DCC; DMAP / CH₂Cl₂ / 2 h / 20 °C

With dmap; sodium hydride; dicyclohexyl-carbodiimide; In dichloromethane; dimethyl sulfoxide;

DOI:10.1021/jo001578u

Reference yield: 59.0%

S-(2-methoxycarbonyl)phenyl [(3,3-diphenyl-prop-2-enyl)oxy]thioacetate (339314-70-4) → 3-biphenylmethyltetrahydrofuran-4-one

Guidance literature:

With tetraethylammonium perchlorate; In N,N-dimethyl-formamide; at 20 ℃; Electrochemical reaction;

DOI:10.1021/jo001578u

upstream raw materials:

Methyl thiosalicylate

benzophenone