10-(4-Bromophenyl)-12,12-dimethyl-10,12dihydro-10-azaindeno[2,1-b]-fluorene

Base Information

• Chemical Name: 10-(4-Bromophenyl)-12,12-dimethyl-10,12dihydro-10-azaindeno[2,1-b]-fluorene
• CAS No.: 1361126-22-8
• Molecular Formula: C₂₇H₂₀BrN
• Molecular Weight: 438.366
• Mol file: 1361126-22-8.mol

Synonyms:10-(4-Bromophenyl)-12,12-dimethyl-10,12dihydro-10-azaindeno[2,1-b]-fluorene

Chemical Property of 10-(4-Bromophenyl)-12,12-dimethyl-10,12dihydro-10-azaindeno[2,1-b]-fluorene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 10-(4-Bromophenyl)-12,12-dimethyl-10,12dihydro-10-azaindeno[2,1-b]-fluorene

There total 10 articles about 10-(4-Bromophenyl)-12,12-dimethyl-10,12dihydro-10-azaindeno[2,1-b]-fluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

1,4-bromoiodobenzene (589-87-7) + 12,12-dimethyl-10,12-dihydro-10-azaindeno[2,1-b]fluorene (1257220-47-5) → 10-(4-Bromophenyl)-12,12-dimethyl-10,12dihydro-10-azaindeno[2,1-b]-fluorene (1361126-22-8)

Guidance literature:

With potassium phosphate; copper(l) iodide; ethylenediamine; In toluene; at 120 ℃; for 18h;

Reference yield: 75.0%

1.4-dibromobenzene (106-37-6) + 12,12-dimethyl-10,12-dihydro-10-azaindeno[2,1-b]fluorene (1257220-47-5) → 10-(4-Bromophenyl)-12,12-dimethyl-10,12dihydro-10-azaindeno[2,1-b]-fluorene (1361126-22-8)

Guidance literature:

With palladium diacetate; caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate; In 5,5-dimethyl-1,3-cyclohexadiene; for 18h; Reflux; Inert atmosphere;

DOI:10.1039/c7pp00350a

Reference yield:

1,4-bromoiodobenzene (589-87-7) + 12,12-dimethyl-10,12-dihydro-10-azaindeno[2,1-b]fluorene + 1-(2-pyridyl)-3-(2-pyridyl)-1,3-propanedione (10198-89-7) → 10-(4-Bromophenyl)-12,12-dimethyl-10,12dihydro-10-azaindeno[2,1-b]-fluorene (1361126-22-8)

Guidance literature:

With potassium carbonate; In tetrahydrofuran; N,N-dimethyl-formamide;

upstream raw materials:

1,4-bromoiodobenzene

12,12-dimethyl-10,12-dihydro-10-azaindeno[2,1-b]fluorene

2-bromo-9,9-dimethyl-9H-fluorene

o-chloroaniline

Downstream raw materials:

C₂₇H₂₂BNO₂

5-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-7,7-dimethyl-5,7-dihydroindeno[2,1-b]carbazole