methyl (tert-butyl 2-O-benzoyl-3,4-di-O-benzyl-α-L-idopyranosyluronate)-(1->4)-[2-azido-3-O-benzyl-2-deoxy-6-O-(4-methoxyphenyl)-α-D-glucopyranosyl]-(1->4)-(tert-butyl 2-O-benzoyl-3-O-benzyl-α-L-idopyranosideuronate)

Base Information

• Chemical Name: methyl (tert-butyl 2-O-benzoyl-3,4-di-O-benzyl-α-L-idopyranosyluronate)-(1->4)-[2-azido-3-O-benzyl-2-deoxy-6-O-(4-methoxyphenyl)-α-D-glucopyranosyl]-(1->4)-(tert-butyl 2-O-benzoyl-3-O-benzyl-α-L-idopyranosideuronate)
• CAS No.: 1075217-45-6
• Molecular Formula: C₇₆H₈₃N₃O₂₀
• Molecular Weight: 1358.5
• Mol file: 1075217-45-6.mol

Synonyms:methyl (tert-butyl 2-O-benzoyl-3,4-di-O-benzyl-α-L-idopyranosyluronate)-(1->4)-[2-azido-3-O-benzyl-2-deoxy-6-O-(4-methoxyphenyl)-α-D-glucopyranosyl]-(1->4)-(tert-butyl 2-O-benzoyl-3-O-benzyl-α-L-idopyranosideuronate)

Chemical Property of methyl (tert-butyl 2-O-benzoyl-3,4-di-O-benzyl-α-L-idopyranosyluronate)-(1->4)-[2-azido-3-O-benzyl-2-deoxy-6-O-(4-methoxyphenyl)-α-D-glucopyranosyl]-(1->4)-(tert-butyl 2-O-benzoyl-3-O-benzyl-α-L-idopyranosideuronate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl (tert-butyl 2-O-benzoyl-3,4-di-O-benzyl-α-L-idopyranosyluronate)-(1->4)-[2-azido-3-O-benzyl-2-deoxy-6-O-(4-methoxyphenyl)-α-D-glucopyranosyl]-(1->4)-(tert-butyl 2-O-benzoyl-3-O-benzyl-α-L-idopyranosideuronate)

There total 1 articles about methyl (tert-butyl 2-O-benzoyl-3,4-di-O-benzyl-α-L-idopyranosyluronate)-(1->4)-[2-azido-3-O-benzyl-2-deoxy-6-O-(4-methoxyphenyl)-α-D-glucopyranosyl]-(1->4)-(tert-butyl 2-O-benzoyl-3-O-benzyl-α-L-idopyranosideuronate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

tert-butyl (phenyl 2-O-benzoyl-3,4-di-O-benzyl-1-thio-α-L-idopyranoside)uronate (1021490-99-2) + methyl [2-azido-3-O-benzyl-2-deoxy-6-O-(4-methoxyphenyl)-α-D-glucopyranosyl]-(1->4)-(tert-butyl 2-O-benzoyl-3-O-benzyl-α-L-idopyranosideuronate) (1075217-44-5) → methyl (tert-butyl 2-O-benzoyl-3,4-di-O-benzyl-α-L-idopyranosyluronate)-(1->4)-[2-azido-3-O-benzyl-2-deoxy-6-O-(4-methoxyphenyl)-α-D-glucopyranosyl]-(1->4)-(tert-butyl 2-O-benzoyl-3-O-benzyl-α-L-idopyranosideuronate) (1075217-45-6)

Guidance literature:

With dimethyl-(methylthio)-sulphonium trifluoromethanesulphonate; In dichloromethane; for 72h; Molecular sieve;

DOI:10.1016/j.tet.2008.08.021

Reference yield: 93.0%

methyl (tert-butyl 2-O-benzoyl-3,4-di-O-benzyl-α-L-idopyranosyluronate)-(1->4)-[2-azido-3-O-benzyl-2-deoxy-6-O-(4-methoxyphenyl)-α-D-glucopyranosyl]-(1->4)-(tert-butyl 2-O-benzoyl-3-O-benzyl-α-L-idopyranosideuronate) (1075217-45-6) → methyl (tert-butyl 3,4-di-O-benzyl-α-L-idopyranosyluronate)-(1->4)-[2-azido-3-O-benzyl-2-deoxy-6-O-(4-methoxyphenyl)-α-D-glucopyranosyl]-(1->4)-(tert-butyl 3-O-benzyl-α-L-idopyranosideuronate) (1075217-48-9)

Guidance literature:

With sodium methylate; In methanol; at 20 ℃; for 168h;

DOI:10.1016/j.tet.2008.08.021

upstream raw materials:

tert-butyl (phenyl 2-O-benzoyl-3,4-di-O-benzyl-1-thio-α-L-idopyranoside)uronate

methyl [2-azido-3-O-benzyl-2-deoxy-6-O-(4-methoxyphenyl)-α-D-glucopyranosyl]-(1->4)-(tert-butyl 2-O-benzoyl-3-O-benzyl-α-L-idopyranosideuronate)

Downstream raw materials:

methyl (tert-butyl 3,4-di-O-benzyl-α-L-idopyranosyluronate)-(1->4)-[2-azido-3-O-benzyl-2-deoxy-6-O-(4-methoxyphenyl)-α-D-glucopyranosyl]-(1->4)-(tert-butyl 3-O-benzyl-α-L-idopyranosideuronate)