Diallylphenylphosphine

Base Information

• Chemical Name: Diallylphenylphosphine
• CAS No.: 29949-75-5
• Molecular Formula: C12H15 P
• Molecular Weight: 190.225
• Hs Code.: 29310099
• European Community (EC) Number: 622-973-6
• DSSTox Substance ID: DTXSID40369901
• Nikkaji Number: J88.640H
• Wikidata: Q72462627
• Mol file: 29949-75-5.mol

Synonyms:Diallylphenylphosphine;29949-75-5;phenyl-bis(prop-2-enyl)phosphane;diallyl(phenyl)phosphine;SCHEMBL624569;DTXSID40369901;phenyl-bis(prop-2-enyl)phosphine;AKOS015910820;FT-0659195;A820123

Chemical Property of Diallylphenylphosphine

Chemical Property:

• Vapor Pressure: 0.0246mmHg at 25°C
• Refractive Index: n20/D 1.568(lit.)
• Boiling Point: 127 °C14 mm Hg(lit.)
• Flash Point: 112.4°C
• PSA: 13.59000
• Density: 0.969 g/mL at 25 °C(lit.)
• LogP: 3.16580
• Storage Temp.: Flammables area
• XLogP3: 2.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 190.091137476
• Heavy Atom Count: 13
• Complexity: 147

Purity/Quality:

98%Min ^*data from raw suppliers

DIALLYLPHENYLPHOSPHINE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xi
• Statements: 17-36/37/38
• Safety Statements: 16-26-27-28-36/37/39-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCP(CC=C)C1=CC=CC=C1

Technology Process of Diallylphenylphosphine

There total 4 articles about Diallylphenylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

Dichlorophenylphosphine (644-97-3) + allylmagnesium bromide (1730-25-2) → diallyl-phenyl-phosphane (29949-75-5)

Guidance literature:

at 0 - 20 ℃; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/acs.organomet.0c00144

Reference yield: 46.0%

allylmagnesium bromide (2622-05-1) + Dichlorophenylphosphine (644-97-3) → diallyl-phenyl-phosphane (29949-75-5)

Guidance literature:

In tetrahydrofuran; at 20 ℃;

DOI:10.1039/c6dt03490j

Reference yield:

di-O,O-menthyl phenylphosphonite (58359-50-5) + allyllithium (3052-45-7) → diallyl-phenyl-phosphane (29949-75-5)

Guidance literature:

Yield given;

DOI:10.1016/0022-328X(86)80033-X

upstream raw materials:

Dichlorophenylphosphine

allylmagnesium bromide

di-O,O-menthyl phenylphosphonite

allyllithium

Downstream raw materials:

C₂₀H₂₇ClPRh

[CoCl₂(bis-allylphenylphosphine)2]

dichlorobis(diallylphenylphosphine)platinum(II)

1-phenyl-2,3-dihydro-1H-phosphole

Refernces

• 1、 -. "Macrocyclic ligands and their complexes for bifunctional molecular catalysis". Page/Page column 81-83. . Retrieved 2019/12/06.
• 2、 Neuffer, J.,Richter, W. J.. "OPTISCH AKTIVE PHOSPHINE DURCH ASYMMETRISCHE SUBSTITUTION PROCHIRALER, HOMOCHIRAL SUBSTITUIERTER PHOSPHONITE". . p. 289 - 298. Retrieved 2007/10/02.