(η5-pentamethylcyclopentadienyl)(diallylphenylphosphine)(1,2-diphosphino-ethane)iron(II) tetrafluoroborate

Base Information

Chemical Name:(η5-pentamethylcyclopentadienyl)(diallylphenylphosphine)(1,2-diphosphino-ethane)iron(II) tetrafluoroborate
CAS No.:298202-48-9
Molecular Formula:BF₄*C₂₄H₃₈FeP₃
Molecular Weight:562.139
Hs Code.:

Synonyms:(η5-pentamethylcyclopentadienyl)(diallylphenylphosphine)(1,2-diphosphino-ethane)iron(II) tetrafluoroborate

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Chemical Property of (η5-pentamethylcyclopentadienyl)(diallylphenylphosphine)(1,2-diphosphino-ethane)iron(II) tetrafluoroborate

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Technology Process of (η5-pentamethylcyclopentadienyl)(diallylphenylphosphine)(1,2-diphosphino-ethane)iron(II) tetrafluoroborate

There total 1 articles about (η5-pentamethylcyclopentadienyl)(diallylphenylphosphine)(1,2-diphosphino-ethane)iron(II) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 298202-46-7
[(η(5)-C5Me5)Fe(1,2-dpe)2(CH3CN)]BF4

: 29949-75-5
diallyl-phenyl-phosphane

: 298202-48-9
(η5-pentamethylcyclopentadienyl)(diallylphenylphosphine)(1,2-diphosphino-ethane)iron(II) tetrafluoroborate

Guidance literature:: In 1,2-dichloro-ethane; (N2); ligand added to a soln. of Fe complex, heated at 80°C for 2h; cooled, evapd. (vac.); obtained as an oil;
DOI:10.1021/om060798g

Reference yield: 35.0%

: 298202-48-9
(η5-pentamethylcyclopentadienyl)(diallylphenylphosphine)(1,2-diphosphino-ethane)iron(II) tetrafluoroborate

: [(C₅(CH₃)5)Fe(HPCH₂)2((CH₂CH₂CH₂)P(C₆H₅)CH₂CH(CH₃))]⁽¹⁺⁾*BF₄^(1-)=[(C₅(CH₃)5)Fe(HPCH₂)2((CH₂CH₂CH₂)P(C₆H₅)CH₂CH(CH₃))]BF₄

Guidance literature:: With azobisisobutyronitrile; In toluene; complex heated in toluene at 80°C in presence of AIBN; isolated by chromy. and anion exchange;
DOI:10.1002/1521-3773(20000804)39:15<2722::AID-ANIE2722>3.0.CO;2-B

Reference yield: 33.0%

: ammonium hexafluorophosphate

: 298202-48-9
(η5-pentamethylcyclopentadienyl)(diallylphenylphosphine)(1,2-diphosphino-ethane)iron(II) tetrafluoroborate

: rac-(η5-pentamethylcyclopentadienyl)(1-phenyl-3-methyl-1,4,7-triphospha-cyclodecane)iron(II) hexafluorophosphate

Guidance literature:: With azoisobutyronitrile; In toluene; (N2); at 90°C for 8 h; cooled, evapd. (vac.), dissolved in CH2Cl2, chromd. (basic alumina, MeOH/CH2Cl2), dried (MgSO4), filtered, volatiles removed, dissolved in MeOH,NH4PF6 added, crystd. at 4°C overnight, filtered, washed (cold M eOH), dried (vac.); elem. anal.;
DOI:10.1021/om060798g