(C₂H₅)3NH⁽¹⁺⁾*(CH₃N(CH₂CH₂NC₆F₅)2)WCl₃^(1-)=((C₂H₅)3NH)((CH₃N(CH₂CH₂NC₆F₅)2)WCl₃)

Base Information

• Chemical Name: (C₂H₅)3NH⁽¹⁺⁾*(CH₃N(CH₂CH₂NC₆F₅)2)WCl₃^(1-)=((C₂H₅)3NH)((CH₃N(CH₂CH₂NC₆F₅)2)WCl₃)
• CAS No.: 282726-75-4
• Molecular Formula: C₆H₁₆N*C₁₇H₁₁Cl₃F₁₀N₃W
• Molecular Weight: 839.687

Synonyms:(C₂H₅)3NH⁽¹⁺⁾*(CH₃N(CH₂CH₂NC₆F₅)2)WCl₃^(1-)=((C₂H₅)3NH)((CH₃N(CH₂CH₂NC₆F₅)2)WCl₃)

Chemical Property of (C₂H₅)3NH⁽¹⁺⁾*(CH₃N(CH₂CH₂NC₆F₅)2)WCl₃^(1-)=((C₂H₅)3NH)((CH₃N(CH₂CH₂NC₆F₅)2)WCl₃)

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Technology Process of (C₂H₅)3NH⁽¹⁺⁾*(CH₃N(CH₂CH₂NC₆F₅)2)WCl₃^(1-)=((C₂H₅)3NH)((CH₃N(CH₂CH₂NC₆F₅)2)WCl₃)

There total 1 articles about (C₂H₅)3NH⁽¹⁺⁾*(CH₃N(CH₂CH₂NC₆F₅)2)WCl₃^(1-)=((C₂H₅)3NH)((CH₃N(CH₂CH₂NC₆F₅)2)WCl₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

tetrachloro(1,2-dimethoxyethane-O,O')tungsten(IV) (146733-16-6) + (C6F5NHCH2CH2)2NCH3 (282726-67-4) + triethylamine (121-44-8) → (C2H5)3NH(1+)*(CH3N(CH2CH2NC6F5)2)WCl3(1-)=((C2H5)3NH)((CH3N(CH2CH2NC6F5)2)WCl3) (282726-75-4)

Guidance literature:

In diethyl ether; WCl4(dme) was added to a soln. of the ligand in Et2O at toom temp., after 30 min NEt3 was added, stirred for 2 h; filtd. through Celite, added to stirred pentane, W-complex was filtered off; X-ray study;

DOI:10.1021/om0001117

Reference yield: 91.0%

(C2H5)3NH(1+)*(CH3N(CH2CH2NC6F5)2)WCl3(1-)=((C2H5)3NH)((CH3N(CH2CH2NC6F5)2)WCl3) (282726-75-4) + tetrabutyl-ammonium chloride (1112-67-0) → (C4H9)4N(1+)*(CH3N(CH2CH2NC6F5)2)WCl3(1-)=((C4H9)4N)((CH3N(CH2CH2NC6F5)2)WCl3) (282726-77-6)

Guidance literature:

In tetrahydrofuran; byproducts: Et3NHCl; under N2; Bu4NCl (1.2 equiv.) added to soln. of W complex in THF; stirred for 12 h; filtered through Celite; volatiles removed from filtrate in vac.; dissolved in toluene; filtered; vol. of filtrate reduced in vac.; added dropwise to rapidly stirred pentane; ppt. collected on frit; washed with pentane; dried in vac.; elem. anal.;

DOI:10.1021/om030638u

Reference yield: 45.0%

(C2H5)3NH(1+)*(CH3N(CH2CH2NC6F5)2)WCl3(1-)=((C2H5)3NH)((CH3N(CH2CH2NC6F5)2)WCl3) (282726-75-4) + 2,2-dimethylpropylmagnesium chloride (13132-23-5) → (CH3N(CH2CH2NC6F5)2)W(CH2C(CH3)3)Cl (671821-34-4)

Guidance literature:

In tetrahydrofuran; under N2; soln. of Mg compd. in THF added to soln. of W complex in THF at -30°C; warmed to room temp. with stirring for 30 min; concd. to dryness in vac.; extd. into toluene; 1,4-dioxane added; stirred for 20 min; filtered through Celite; filtrate added dropwise to cold stirred pentane; ppt. collected on frit; washed with pentane; dried in vac.; elem. anal.;

DOI:10.1021/om030638u

upstream raw materials:

tetrachloro(1,2-dimethoxyethane-O,O')tungsten(IV)

(C₆F₅NHCH₂CH₂)2NCH₃

triethylamine

Downstream raw materials:

(C₄H₉)4N⁽¹⁺⁾*(CH₃N(CH₂CH₂NC₆F₅)2)WCl₃^(1-)=((C₄H₉)4N)((CH₃N(CH₂CH₂NC₆F₅)2)WCl₃)

(CH₃N(CH₂CH₂NC₆F₅)2)W(CH₂C(CH₃)3)Cl

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