13132-23-5

Basic information

• Product Name: NEOPENTYLMAGNESIUM CHLORIDE
• Synonyms: 2,2-Dimethylpropylmagnesium chloride solution 1.0 in diethyl ether;NeopentylMagnesiuM chloride, 1.0M in 2-MeTHF;MagnesiuM,chloro(2,2-diMethylpropyl)-(9CI);2,2-Dimethylpropylmagnesium choride 1M solution in DEE;2,2-Dimethylpropylmagnesium chloride solution 1.0 M in THF;NEOPENTYLMAGNESIUM CHLORIDE;2,2-DIMETHYLPROPYLMAGNESIUM CHLORIDE;2,2-DIMETHYLPROPYLMAGNESIUM CHLORIDE,1.0M SOLUTION IN DIETHYL ETHER
• CAS NO: 13132-23-5
• Molecular Formula: C₅H₁₁ClMg
• Molecular Weight: 130.9
• Product Categories: Grignard Reagent
• Mol File: 13132-23-5.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 7.2°C at 760 mmHg
• Flash Point: −26 °F
• Appearance: /
• Density: 0.771 g/mL at 25 °C
• Vapor Pressure: 1420mmHg at 25°C
• Storage Temp.: 2-8°C
• CAS DataBase Reference: NEOPENTYLMAGNESIUM CHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: NEOPENTYLMAGNESIUM CHLORIDE(13132-23-5)
• EPA Substance Registry System: NEOPENTYLMAGNESIUM CHLORIDE(13132-23-5)

Safety Data

• Hazard Codes: F+,C,F
• Statements: 12-14-19-22-34-67-14/15-11-40-37
• Safety Statements: 16-26-36/37/39-45-43
• RIDADR: UN 3399 4.3/PG 1
• WGK Germany: 3
• Hazardous Substances Data: 13132-23-5(Hazardous Substances Data)

Usage

General Description

NEOPENTYLMAGNESIUM CHLORIDE is a chemical compound that consists of a magnesium atom bonded to three neopentyl groups and one chloride ion. It is commonly used as a reagent in organic synthesis for the formation of carbon-carbon and carbon-heteroatom bonds. This reagent is particularly useful in Grignard reactions, which are a type of chemical reaction that involves the addition of a magnesium halide to a carbonyl compound, resulting in the formation of a new carbon-carbon bond. NEOPENTYLMAGNESIUM CHLORIDE is a versatile and efficient reagent that has found wide application in the preparation of various organic compounds in laboratory and industrial settings.

InChI:InChI=1/C5H11.ClH.Mg/c1-5(2,3)4;;/h1H2,2-4H3;1H;/q-1;;+2/p-1

Upstream product

• 60-29-7 diethyl ether 
• 753-89-9 neopentyl chloride 

Downstream Products

• 15501-33-4 neopentyl iodide 
• 53333-76-9 2,2-dimethyl-propane-1-sulfonyl chloride 
• 624-95-3 3,3-dimethylbutanol 
• 57620-68-5 Bis-neopentyl-phenylphosphin 
• 281-23-2 adamantane 
• 111035-09-7 neopentyl-1 adamantane 
• 1679-08-9 2,2-dimethylpropylthiol 
• 68890-62-0 Methyl-neopentyl-phenyl-phosphin-oxid 
• 1070-83-3 tert-Butylacetic acid 
• 4379-33-3 2-(tert-butyl)malonic acid 
• 10284-49-8 Dineopentyl-quecksilber 
• 690-92-6 cis-2,2-dimethyl-3-hexene 
• 908247-24-5 4-((E)-3,3-Dimethyl-but-1-enyl)-benzoic acid 
• 60633-21-8 di-tert-butyl(neopentyl)phosphine 

Relevant articles and documents

Active Magnesium from Catalytically Prepared Magnesium Hydride or from Magnesium Anthracene and its Uses in the Synthesis

Highly reactive, pyrophoric forms of magnesium with specific surface areas of 20-109 m2/g (Mg*) can be generated by the dehydrogenation of catalytically prepared magnesium hydride (MgH2*) or by decomposition of magnesium anthracene * 3 THF (4).The decomposition of 4, with recovery of anthracene and THF, may be accomplished both thermally and by ultrasound in an organic solvent (toluene, n-heptane) or thermally in the solid state in vacuo.Mg* obtained by the latter method exhibits only weak reflections in the X-ray powder diagram and has, in comparison to other mentioned Mg* species, the highest reactivity toward hydrogen.Diverse Grignard compounds can be prepared under mild conditions (* from MgH2* or 4.The cleavage of THF with formation of 1-oxa-2-magnesiacyclohexane (2) is possible by employing Mg* from NgH2* or 4.