2-(p-methoxyphenyl)-9-(5'-methylpyridin-2'-yl)-1,10-phenanthroline

Base Information

• Chemical Name: 2-(p-methoxyphenyl)-9-(5'-methylpyridin-2'-yl)-1,10-phenanthroline
• CAS No.: 201403-32-9
• Molecular Formula: C₂₅H₁₉N₃O
• Molecular Weight: 377.445
• Mol file: 201403-32-9.mol

Synonyms:2-(p-methoxyphenyl)-9-(5'-methylpyridin-2'-yl)-1,10-phenanthroline

Chemical Property of 2-(p-methoxyphenyl)-9-(5'-methylpyridin-2'-yl)-1,10-phenanthroline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(p-methoxyphenyl)-9-(5'-methylpyridin-2'-yl)-1,10-phenanthroline

There total 1 articles about 2-(p-methoxyphenyl)-9-(5'-methylpyridin-2'-yl)-1,10-phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

2-Bromo-5-methylpyridine (3510-66-5) + 2-(4'-methoxyphenyl)-1,10-phenanthroline (142942-21-0) → 2-(p-methoxyphenyl)-9-(5'-methylpyridin-2'-yl)-1,10-phenanthroline (201403-32-9)

Guidance literature:

With n-butyllithium; In diethyl ether; hexane; at 0 - 10 ℃; for 6h;

DOI:10.1002/(sici)1099-0682(200001)2000:1<113::aid-ejic113>3.0.co;2-9

Reference yield: 87.0%

potassium hexafluorophosphate (17084-13-8) + Ru(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)Cl3 (259251-59-7) + 2-(p-methoxyphenyl)-9-(5'-methylpyridin-2'-yl)-1,10-phenanthroline (201403-32-9) → bis(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)ruthenium(II) dihexafluorophosphate

Guidance literature:

With N-ethylmorpholine; In water; acetic acid; suspn. of Ru-complex and ligand in glacial acetic acid with 2-3 drops ofN-ethylmorpholine was refluxed under Ar for 3 h; solvent removed under reduced pressure, solid redissolved in MeOH, filtered, aq. soln. of KPF6 was added, silica gel chromy., eluted with CH2Cl2/CH3OH; elem. anal.;

DOI:10.1002/(sici)1099-0682(200001)2000:1<113::aid-ejic113>3.0.co;2-9

Reference yield: 84.0%

ruthenium(III) chloride trihydrate (14898-67-0) + 2-(p-methoxyphenyl)-9-(5'-methylpyridin-2'-yl)-1,10-phenanthroline (201403-32-9) → Ru(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)Cl3 (259251-59-7)

Guidance literature:

In ethanol; to abs. EtOH were added RuCl3*3H2O and ligand, mixt. heated at reflux for 3 h with vigorous stirring, mixt. was cooled to room temp.; ppt. was collected by vac. filtration, washed with abs. EtOH, followed by Et2O, dried under vac.;

DOI:10.1002/(sici)1099-0682(200001)2000:1<113::aid-ejic113>3.0.co;2-9

upstream raw materials:

2-Bromo-5-methylpyridine

2-(4'-methoxyphenyl)-1,10-phenanthroline

Downstream raw materials:

Ru(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)Cl₃

Cu(CH₃OC₆H₄C₁₂H₆N₂C₅H₃NCH₃)2⁽¹⁺⁾*PF₆^(1-)=[Cu(CH₃OC₆H₄C₁₂H₆N₂C₅H₃NCH₃)2]PF₆