5-pentafluorophenyl-1,9-bis(triisopropylsilyl)-1,9-diaza-10,11-dicarbadipyrromethane

Base Information

Chemical Name:5-pentafluorophenyl-1,9-bis(triisopropylsilyl)-1,9-diaza-10,11-dicarbadipyrromethane
CAS No.:1327160-31-5
Molecular Formula:C₃₃H₄₉F₅N₂Si₂
Molecular Weight:624.928
Hs Code.:

Synonyms:5-pentafluorophenyl-1,9-bis(triisopropylsilyl)-1,9-diaza-10,11-dicarbadipyrromethane

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Chemical Property of 5-pentafluorophenyl-1,9-bis(triisopropylsilyl)-1,9-diaza-10,11-dicarbadipyrromethane

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Technology Process of 5-pentafluorophenyl-1,9-bis(triisopropylsilyl)-1,9-diaza-10,11-dicarbadipyrromethane

There total 1 articles about 5-pentafluorophenyl-1,9-bis(triisopropylsilyl)-1,9-diaza-10,11-dicarbadipyrromethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.8%

: 653-37-2
perfluorobenzaldehyde

: 87630-35-1
N-triisopropylsilylpyrrole

: 1327160-31-5
5-pentafluorophenyl-1,9-bis(triisopropylsilyl)-1,9-diaza-10,11-dicarbadipyrromethane

: 1327160-32-6
5-pentafluorophenyl-1,11-bis(triisopropylsilyl)-1-aza-10-carbadipyrromethane

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at 0 ℃; for 0.0833333h; regioselective reaction; Inert atmosphere;
DOI:10.1021/jo2014017

Reference yield: 93.0%

: 1327160-31-5
5-pentafluorophenyl-1,9-bis(triisopropylsilyl)-1,9-diaza-10,11-dicarbadipyrromethane

: 1327160-33-7
5-pentafluorophenyl-1,9-diaza-10,11-dicarbadipyrromethane

Guidance literature:: 5-pentafluorophenyl-1,9-bis(triisopropylsilyl)-1,9-diaza-10,11-dicarbadipyrromethane; With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 1.5h; Inert atmosphere;

With water; In tetrahydrofuran;
DOI:10.1021/jo2014017

Reference yield:

: 1327160-31-5
5-pentafluorophenyl-1,9-bis(triisopropylsilyl)-1,9-diaza-10,11-dicarbadipyrromethane

: 1379604-96-2
C₂₉H₁₁F₁₅N₂O₂

Guidance literature:: Multi-step reaction with 3 steps

1.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 1.5 h / 20 °C / Inert atmosphere

2.1: ethylmagnesium bromide / tetrahydrofuran / 0.17 h / 20 °C / Inert atmosphere

2.2: 2.62 h / -78 - 20 °C / Inert atmosphere

2.3: 20 °C / Saturated solution

3.1: sodium tetrahydroborate / tetrahydrofuran; methanol / 3 h / 20 °C / Inert atmosphere

3.2: 20 °C

With sodium tetrahydroborate; ethylmagnesium bromide; tetrabutyl ammonium fluoride; In tetrahydrofuran; methanol;
DOI:10.1021/jo2014017