zinc meso-phenyltetrabenzotriazaporphyrin

Base Information

• Chemical Name: zinc meso-phenyltetrabenzotriazaporphyrin
• CAS No.: 869644-61-1
• Molecular Formula: C₃₉H₂₁N₇Zn
• Molecular Weight: 653.033
• Mol file: 869644-61-1.mol

Synonyms:zinc meso-phenyltetrabenzotriazaporphyrin

Chemical Property of zinc meso-phenyltetrabenzotriazaporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of zinc meso-phenyltetrabenzotriazaporphyrin

There total 1 articles about zinc meso-phenyltetrabenzotriazaporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

phenylacetic acid (103-82-2) + isoindole-1,3-diylidenediamine (160956-25-2,160956-26-3,160956-27-4,160956-28-5,160956-29-6) + zinc(II) oxide → zinc meso-phenyltetrabenzotriazaporphyrin (869644-61-1) + zinc meso-cis-diphenyltetrabenzodiazaporphyrin (869644-59-7) + zinc meso-trans-diphenyltetrabenzodiazaporphyrin (869644-60-0) + zinc meso-triphenyltetrabenzoazaporphyrin (869644-58-6)

Guidance literature:

With potassium hydroxide; In melt; a mixt. of isoindoline-1,3-diimine, phenylacetic acid, and zinc oxide was heated in a quartz tube at 280°C for 1 h; the melt was cooled, ground and refluxed for 10 min in aq. KOH soln.; the melt was cooled, ground, refluxed for 10 min in aq. KOH soln., filtered off, washed with water to neutral washings, and dried; column chromy. (alumina, eluent: toluene-acetone, 10:1); elem. anal.;

DOI:10.1007/s11176-005-0289-8

Reference yield: 96.0%

zinc meso-phenyltetrabenzotriazaporphyrin (869644-61-1) → 27-phenyl-29H,31H-tetrabenzo[b,g,l,q][5,10,15]triazaporphyrine (129204-89-3)

Guidance literature:

With pyridine hydrochloride; In pyridine; for 3h; Reflux;

DOI:10.1039/c3dt51357b

upstream raw materials:

phenylacetic acid

isoindole-1,3-diylidenediamine

Downstream raw materials:

27-phenyl-29H,31H-tetrabenzo[b,g,l,q][5,10,15]triazaporphyrine