methyl 2,3-dideoxy-5,6-O-isopropylidene-4-O-p-tolylsulfonyl-D-erythro-hexonate

Base Information

Chemical Name:methyl 2,3-dideoxy-5,6-O-isopropylidene-4-O-p-tolylsulfonyl-D-erythro-hexonate
CAS No.:136963-32-1
Molecular Formula:C₁₇H₂₄O₇S
Molecular Weight:372.439
Hs Code.:

Synonyms:methyl 2,3-dideoxy-5,6-O-isopropylidene-4-O-p-tolylsulfonyl-D-erythro-hexonate

Suppliers and Price of methyl 2,3-dideoxy-5,6-O-isopropylidene-4-O-p-tolylsulfonyl-D-erythro-hexonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 2,3-dideoxy-5,6-O-isopropylidene-4-O-p-tolylsulfonyl-D-erythro-hexonate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of methyl 2,3-dideoxy-5,6-O-isopropylidene-4-O-p-tolylsulfonyl-D-erythro-hexonate

There total 2 articles about methyl 2,3-dideoxy-5,6-O-isopropylidene-4-O-p-tolylsulfonyl-D-erythro-hexonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.5%

: 127553-90-6
methyl 2,3-dideoxy-5,6-O-isopropylidene-D-erythro-hexonate

: 98-59-9
p-toluenesulfonyl chloride

: 136963-32-1
methyl 2,3-dideoxy-5,6-O-isopropylidene-4-O-p-tolylsulfonyl-D-erythro-hexonate

Guidance literature:: With pyridine; at 5 ℃; for 48h;
DOI:10.1016/0008-6215(92)84152-I

Reference yield:

: 127529-99-1
(S)-Chloro-((4R,5S,4'R)-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-acetic acid methyl ester

: 136963-32-1
methyl 2,3-dideoxy-5,6-O-isopropylidene-4-O-p-tolylsulfonyl-D-erythro-hexonate

Guidance literature:: Multi-step reaction with 2 steps

1: 1) NaOAc, 2) H₂ / 10percent Pd/C / 1) MeOH, reflux, overnight, 2) r.t., 1 atm, 4 h

2: 66.5 percent / pyridine / 48 h / 5 °C

With pyridine; hydrogen; sodium acetate; palladium on activated charcoal;
DOI:10.1016/0008-6215(92)84152-I