N-(3-chloro-4-methylphenyl) N-(4-methylphenylsulfonyl)hydroxylamine

Base Information

• Chemical Name: N-(3-chloro-4-methylphenyl) N-(4-methylphenylsulfonyl)hydroxylamine
• CAS No.: 135961-81-8
• Molecular Formula: C₁₄H₁₄ClNO₃S
• Molecular Weight: 311.789
• Mol file: 135961-81-8.mol

Synonyms:N-(3-chloro-4-methylphenyl) N-(4-methylphenylsulfonyl)hydroxylamine

Chemical Property of N-(3-chloro-4-methylphenyl) N-(4-methylphenylsulfonyl)hydroxylamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-(3-chloro-4-methylphenyl) N-(4-methylphenylsulfonyl)hydroxylamine

There total 3 articles about N-(3-chloro-4-methylphenyl) N-(4-methylphenylsulfonyl)hydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-(3-chloro-4-methylphenyl)hydroxylamine (34634-76-9) + p-toluenesulfonyl chloride (98-59-9) → p-toluene sulfinic acid (536-57-2) + 1,2-bis(3-chloro-4-methylphenyl)diazene oxide (65655-68-7) + N-(3-chloro-4-methylphenyl) N-(4-methylphenylsulfonyl)hydroxylamine (135961-81-8)

Guidance literature:

In acetic acid; acetonitrile;

Reference yield:

2-chloro-4-nitrotoluene (121-86-8) → N-(3-chloro-4-methylphenyl) N-(4-methylphenylsulfonyl)hydroxylamine (135961-81-8)

Guidance literature:

Multi-step reaction with 2 steps

1: acetic buffer / ethanol / electrolysis

2: 3.1 g / ethanol

With acetic buffer; In ethanol;

Reference yield:

2-chloro-1-methyl-4-nitrosobenzene (65655-67-6) + sodium 4-methylbenzenesulfinate (824-79-3) → N-(3-chloro-4-methylphenyl) N-(4-methylphenylsulfonyl)hydroxylamine (135961-81-8)

Guidance literature:

In ethanol;

upstream raw materials:

2-chloro-1-methyl-4-nitrosobenzene

sodium 4-methylbenzenesulfinate

N-(3-chloro-4-methylphenyl)hydroxylamine

p-toluenesulfonyl chloride

Downstream raw materials:

p-toluene sulfinic acid

2-chloro-1-methyl-4-nitrosobenzene