2-iodo-1,3,5,7-tetramethyl-8-phenyl-4,4-difluoro-4-bora-3a-azonia-4a-aza-s-indacence

Base Information

• Chemical Name: 2-iodo-1,3,5,7-tetramethyl-8-phenyl-4,4-difluoro-4-bora-3a-azonia-4a-aza-s-indacence
• CAS No.: 1296869-56-1
• Molecular Formula: C₁₉H₁₈BF₂IN₂
• Molecular Weight: 450.078

Synonyms:2-iodo-1,3,5,7-tetramethyl-8-phenyl-4,4-difluoro-4-bora-3a-azonia-4a-aza-s-indacence

Chemical Property of 2-iodo-1,3,5,7-tetramethyl-8-phenyl-4,4-difluoro-4-bora-3a-azonia-4a-aza-s-indacence

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-iodo-1,3,5,7-tetramethyl-8-phenyl-4,4-difluoro-4-bora-3a-azonia-4a-aza-s-indacence

There total 9 articles about 2-iodo-1,3,5,7-tetramethyl-8-phenyl-4,4-difluoro-4-bora-3a-azonia-4a-aza-s-indacence which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

phenyl BODIPY → 2-iodo-1,3,5,7-tetramethyl-8-phenyl-4,4-difluoro-4-bora-3a-azonia-4a-aza-s-indacence (1296869-56-1)

Guidance literature:

With calcium carbonate; benzyl triethylammonium dichloroiodate; In methanol; dichloromethane; at 20 ℃; for 1h;

DOI:10.1021/jo200491m

Reference yield: 76.0%

N-iodo-succinimide (516-12-1) + phenyl BODIPY → 2-iodo-1,3,5,7-tetramethyl-8-phenyl-4,4-difluoro-4-bora-3a-azonia-4a-aza-s-indacence (1296869-56-1)

Guidance literature:

In dichloromethane; (N2); addn. of iodosuccinimide to soln. of boron compd. in amhyd. CH2Cl2, stirring at room temp. for 30 min; addn. of aq. satd. soln. of NaCl, extn. (CH2Cl2), drying over Na2SO4, filtration, concg., chromy. (silica gel, petroleum ether/CH2Cl2 (2/1)), NMR;

DOI:10.1039/c1ob05959a

Reference yield:

2,4-dimethyl-1H-pyrrole (625-82-1) → 2-iodo-1,3,5,7-tetramethyl-8-phenyl-4,4-difluoro-4-bora-3a-azonia-4a-aza-s-indacence (1296869-56-1)

Guidance literature:

Multi-step reaction with 2 steps

1.1: dichloromethane / 20 °C / Inert atmosphere

1.2: 1 h / Inert atmosphere; Cooling with ice

2.1: N-iodo-succinimide / dichloromethane / 1 h / 10 - 20 °C

With N-iodo-succinimide; In dichloromethane;

DOI:10.1021/jo200990y

upstream raw materials:

2,4-dimethyl-1H-pyrrole

benzoyl chloride

N-iodo-succinimide

3,3',5,5'-tetramethyl-6-phenylpyrromethene

Downstream raw materials:

meta-BAEB

para-BAEB

2-ethynyl-5,5-difluoro-1,3,7,9-tetramethyl-10-phenyl-5H-4λ⁴,5λ⁴-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinine

ortho-BAEB

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 1296869-56-1 2-iodo-1,3,5,7-tetramethyl-8-phenyl-4,4-difluoro-4-bora-3a-azonia-4a-aza-s-indacence

Send

Send

Metric Ton KG G Pound L ML

Send

Send