Ni(CO)3(η1-dppm)

Base Information

• Chemical Name: Ni(CO)3(η1-dppm)
• CAS No.: 62945-83-9
• Molecular Formula: C₂₈H₂₂NiO₃P₂
• Molecular Weight: 527.118
• Mol file: 62945-83-9.mol

Synonyms:Ni(CO)3(η1-dppm)

Chemical Property of Ni(CO)3(η1-dppm)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ni(CO)3(η1-dppm)

There total 6 articles about Ni(CO)3(η1-dppm) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Ni(CO)2(HC(P(C6H5)2)3) (75790-05-5) → Ni(CO)3(η1-dppm) (62945-83-9)

Guidance literature:

Multi-step reaction with 2 steps

1: oxygen / benzene; tetrahydrofuran

With oxygen; In tetrahydrofuran; benzene;

DOI:10.1021/ja00215a018

Reference yield:

Tris(diphenylphosphino)methan (28926-65-0) → Ni(CO)3(η1-dppm) (62945-83-9) + Ni2(CO)4(CH2(P(C6H5)2)2)2 (112896-40-9)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

In tetrahydrofuran;

DOI:10.1021/ja00215a018

Reference yield:

Ni2(CO)4(CH2(P(C6H5)2)2)2 (112896-40-9) + carbon monoxide (201230-82-2) → Ni(CO)3(η1-dppm) (62945-83-9)

Guidance literature:

In not given; investigation of CO-uptake at 25°C/700 torr resp. 2.5 atm;; not isolated; 55% (at 700 torr) resp. 100% (at 2.5 atm) conversion (determined by 31P-NMR);;

DOI:10.1016/S0020-1693(00)85531-0

upstream raw materials:

tricarbonylbis(bis(diphenylphosphino)methane)dinickel⁽⁰⁾

carbon monoxide

(1η-dpm)2Ni(CO)2

Ni₂(CO)4(CH₂(P(C₆H₅)2)2)2

Downstream raw materials:

Ni₂(CO)4(CH₂(P(C₆H₅)2)2)2

carbon monoxide