C₂₇H₃₀O₆S₂

Base Information

• Chemical Name: C₂₇H₃₀O₆S₂
• CAS No.: 1283096-04-7
• Molecular Formula: C₂₇H₃₀O₆S₂
• Molecular Weight: 514.664
• Mol file: 1283096-04-7.mol

Synonyms:C₂₇H₃₀O₆S₂

Chemical Property of C₂₇H₃₀O₆S₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of C₂₇H₃₀O₆S₂

There total 3 articles about C₂₇H₃₀O₆S₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

(+/-)-3-(4-methoxyphenyl)-4-methylpentanal (309271-51-0) + 1,1-bis(phenylsulfonyl)ethylene (39082-53-6) → C27H30O6S2 (1283096-04-7) + C27H30O6S2

Guidance literature:

With (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine; acetic acid; In tetrahydrofuran; chloroform; at 23 ℃; for 2h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;

DOI:10.1002/anie.201007001

Reference yield:

C13H18O2 → C27H30O6S2 (1283096-04-7) + C27H30O6S2

Guidance literature:

Multi-step reaction with 2 steps

1: C₂₆H₄₀IrNOP⁽¹⁺⁾*C₃₂H₁₂BF₂₄^(1-); hydrogen / tetrahydrofuran / 22 h / 23 °C

2: (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine; acetic acid / tetrahydrofuran; chloroform / 2 h / 23 °C / Inert atmosphere

With (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine; C₂₆H₄₀IrNOP⁽¹⁺⁾*C₃₂H₁₂BF₂₄^(1-); hydrogen; acetic acid; In tetrahydrofuran; chloroform;

DOI:10.1002/anie.201007001

Reference yield:

bis(phenylsulfonyl)methane (3406-02-8) → C27H30O6S2 (1283096-04-7) + C27H30O6S2

Guidance literature:

Multi-step reaction with 2 steps

1: piperidine / methanol; water / 1.17 h / 0 °C / Inert atmosphere

2: (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine; acetic acid / tetrahydrofuran; chloroform / 2 h / 23 °C / Inert atmosphere

With piperidine; (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine; acetic acid; In tetrahydrofuran; methanol; chloroform; water;

DOI:10.1002/anie.201007001

upstream raw materials:

(+/-)-3-(4-methoxyphenyl)-4-methylpentanal

1,1-bis(phenylsulfonyl)ethylene

bis(phenylsulfonyl)methane