C₃₀H₅₀O₈Si

Base Information

• Chemical Name: C₃₀H₅₀O₈Si
• CAS No.: 950190-80-4
• Molecular Formula: C₃₀H₅₀O₈Si
• Molecular Weight: 566.808
• Mol file: 950190-80-4.mol

Synonyms:C₃₀H₅₀O₈Si

Chemical Property of C₃₀H₅₀O₈Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₀H₅₀O₈Si

There total 6 articles about C₃₀H₅₀O₈Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

C36H62O6S4Si (950190-84-8) → C30H50O8Si (950190-80-4)

Guidance literature:

With mercury(II) perchlorate; calcium carbonate; In tetrahydrofuran; water; at 0 ℃; for 0.0833333h;

DOI:10.1021/ol071282b

Reference yield:

methyl 3,4,6-tri-O-acetyl-2-deoxy-α/β-D-glucopyranoside (126873-07-2) → C30H50O8Si (950190-80-4)

Guidance literature:

Multi-step reaction with 5 steps

1.1: hydrogen / palladium on carbon / ethyl acetate; ethanol

1.2: sodium methoxide / methanol / 3 h / 20 °C

1.3: 6.65 g / conc. HCl / CHCl₃ / 0.5 h / 20 °C

2.1: 70 percent / p-toluenesulfonic acid monohydrate / acetone / 2 h / -25 °C

3.1: 84 percent / sodium hydride / tetrahydrofuran / 2.5 h / 0 - 20 °C

4.1: potassium tert-butoxide; n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C

4.2: tetrahydrofuran; hexane / 2 h / -78 °C

4.3: 77 percent / tetrahydrofuran; hexane / 0.83 h / -78 - 0 °C

5.1: 75 percent / calcium carbonate; mercury(II) perchlorate trihydrate / tetrahydrofuran; H₂O / 0.08 h / 0 °C

With n-butyllithium; mercury(II) perchlorate; potassium tert-butylate; hydrogen; sodium hydride; toluene-4-sulfonic acid; calcium carbonate; palladium on activated charcoal; In tetrahydrofuran; ethanol; hexane; water; ethyl acetate; acetone;

DOI:10.1021/ol071282b

Reference yield:

D-glucal triacetate (2873-29-2) → C30H50O8Si (950190-80-4)

Guidance literature:

Multi-step reaction with 6 steps

1.1: BF₃*OEt₂ / CH₂Cl₂ / 1 h / 0 - 20 °C

2.1: hydrogen / palladium on carbon / ethyl acetate; ethanol

2.2: sodium methoxide / methanol / 3 h / 20 °C

2.3: 6.65 g / conc. HCl / CHCl₃ / 0.5 h / 20 °C

3.1: 70 percent / p-toluenesulfonic acid monohydrate / acetone / 2 h / -25 °C

4.1: 84 percent / sodium hydride / tetrahydrofuran / 2.5 h / 0 - 20 °C

5.1: potassium tert-butoxide; n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C

5.2: tetrahydrofuran; hexane / 2 h / -78 °C

5.3: 77 percent / tetrahydrofuran; hexane / 0.83 h / -78 - 0 °C

6.1: 75 percent / calcium carbonate; mercury(II) perchlorate trihydrate / tetrahydrofuran; H₂O / 0.08 h / 0 °C

With n-butyllithium; mercury(II) perchlorate; boron trifluoride diethyl etherate; potassium tert-butylate; hydrogen; sodium hydride; toluene-4-sulfonic acid; calcium carbonate; palladium on activated charcoal; In tetrahydrofuran; ethanol; hexane; dichloromethane; water; ethyl acetate; acetone;

DOI:10.1021/ol071282b

upstream raw materials:

C₃₆H₆₂O₆S₄Si

C₁₃H₂₄O₃S₂

C₉H₁₈O₃S₂

C₁₂H₂₂O₃S₂

Downstream raw materials:

C₂₁H₃₀O₆

C₃₇H₄₈O₆Si

C₄₄H₅₄O₆Si

C₄₄H₅₄O₇Si