diallylphosphinic acid benzyl ester

Base Information

• Chemical Name: diallylphosphinic acid benzyl ester
• CAS No.: 222419-77-4
• Molecular Formula: C₁₃H₁₇O₂P
• Molecular Weight: 236.251
• Mol file: 222419-77-4.mol

Synonyms:diallylphosphinic acid benzyl ester

Chemical Property of diallylphosphinic acid benzyl ester

Chemical Property:

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Technology Process of diallylphosphinic acid benzyl ester

There total 1 articles about diallylphosphinic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diallyl phosphinic acid (35622-32-3) + benzyl alcohol (100-51-6,185532-71-2) → diallylphosphinic acid benzyl ester (222419-77-4)

Guidance literature:

With dmap; oxalyl dichloride; triethylamine; N,N-dimethyl-formamide; Yield given; Multistep reaction; 1.) CH₂Cl₂, room temp., 1 h, 2.) CH₂Cl₂, -78 deg C to room temp., 4 h;

DOI:10.1021/jo981795j

Reference yield: 95.0%

diallylphosphinic acid benzyl ester (222419-77-4) → 1-benzyloxy-2,5-dihydro-phosphole 1-oxide (163929-68-8)

Guidance literature:

With 2,6-diisopropylphenylimidoneophylidene molybdenum(VI) bis(hexafluoro-tert-butoxide); In toluene; Heating;

DOI:10.1021/jo981795j

Reference yield: 60.0%

diallylphosphinic acid benzyl ester (222419-77-4) + methyl iodide (74-88-4) → allyl(1-methylallyl)phosphinic acid benzyl ester (222419-83-2)

Guidance literature:

With N,N,N,N,-tetramethylethylenediamine; lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 0.25h;

DOI:10.1021/jo981795j

upstream raw materials:

diallyl phosphinic acid

benzyl alcohol

Downstream raw materials:

1-benzyloxy-2,5-dihydro-phosphole 1-oxide

allyl(1-methylallyl)phosphinic acid benzyl ester