(Z)-3-(5-(tert-butyldimethylsilyloxy)-7-phenylnaphtho[2,3-d][1,3]dioxol-6-yl)acrylaldehyde

Base Information

Chemical Name:(Z)-3-(5-(tert-butyldimethylsilyloxy)-7-phenylnaphtho[2,3-d][1,3]dioxol-6-yl)acrylaldehyde
CAS No.:1357264-46-0
Molecular Formula:C₂₆H₂₈O₄Si
Molecular Weight:432.591
Hs Code.:

Synonyms:(Z)-3-(5-(tert-butyldimethylsilyloxy)-7-phenylnaphtho[2,3-d][1,3]dioxol-6-yl)acrylaldehyde

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Chemical Property of (Z)-3-(5-(tert-butyldimethylsilyloxy)-7-phenylnaphtho[2,3-d][1,3]dioxol-6-yl)acrylaldehyde

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Technology Process of (Z)-3-(5-(tert-butyldimethylsilyloxy)-7-phenylnaphtho[2,3-d][1,3]dioxol-6-yl)acrylaldehyde

There total 2 articles about (Z)-3-(5-(tert-butyldimethylsilyloxy)-7-phenylnaphtho[2,3-d][1,3]dioxol-6-yl)acrylaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 1357264-80-2
tert-butyl(furan-2-yl(6-(phenylethynyl)benzo[d][1,3]dioxol-5-yl)methoxy)dimethylsilane

: 1357264-46-0
(Z)-3-(5-(tert-butyldimethylsilyloxy)-7-phenylnaphtho[2,3-d][1,3]dioxol-6-yl)acrylaldehyde

Guidance literature:: With Echavarren's catalyst; In toluene; at 20 ℃; for 2h; optical yield given as %de; stereoselective reaction;
DOI:10.1021/jo202541p

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1357264-46-0
(Z)-3-(5-(tert-butyldimethylsilyloxy)-7-phenylnaphtho[2,3-d][1,3]dioxol-6-yl)acrylaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 1H-imidazole / dichloromethane / 1 h / 20 °C

2: Echavarren's catalyst / toluene / 2 h / 20 °C

With 1H-imidazole; Echavarren's catalyst; In dichloromethane; toluene;
DOI:10.1021/jo202541p