4-[(3Z,9E)-7-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-8-methylene-deca-3,9-diene-1,5-diynyl]-[1,3]dioxol-2-one

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Chemical Name:4-[(3Z,9E)-7-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-8-methylene-deca-3,9-diene-1,5-diynyl]-[1,3]dioxol-2-one
CAS No.:126629-14-9
Molecular Formula:C₂₈H₃₂O₆Si
Molecular Weight:492.644
Hs Code.:

Synonyms:4-[(3Z,9E)-7-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-8-methylene-deca-3,9-diene-1,5-diynyl]-[1,3]dioxol-2-one

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Chemical Property of 4-[(3Z,9E)-7-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-8-methylene-deca-3,9-diene-1,5-diynyl]-[1,3]dioxol-2-one

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Technology Process of 4-[(3Z,9E)-7-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-8-methylene-deca-3,9-diene-1,5-diynyl]-[1,3]dioxol-2-one

There total 5 articles about 4-[(3Z,9E)-7-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-8-methylene-deca-3,9-diene-1,5-diynyl]-[1,3]dioxol-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: 65842-65-1
bromovinylene carbonate

: 126629-13-8
tert-Butyl-{(Z)-1-[(E)-3-(4-methoxy-benzyloxy)-1-methylene-allyl]-hept-4-ene-2,6-diynyloxy}-dimethyl-silane

: 126629-14-9
4-[(3Z,9E)-7-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-8-methylene-deca-3,9-diene-1,5-diynyl]-[1,3]dioxol-2-one

Guidance literature:: With copper(l) iodide; TEA; dichloro bis(acetonitrile) palladium(II); In benzene;
DOI:10.1016/S0040-4039(01)80649-3

Reference yield:

: 126629-11-6
(Z)-7-[Dimethyl-(1,1,2-trimethyl-propyl)-silanyl]-hept-4-ene-2,6-diynal

: 126629-14-9
4-[(3Z,9E)-7-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-8-methylene-deca-3,9-diene-1,5-diynyl]-[1,3]dioxol-2-one

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) n-BuLi, MgBr₂ / 1.) THF, -78 deg C

2: nBu₄NF / tetrahydrofuran / 0 °C

3: Et₃N / CH₂Cl₂ / 0 °C

4: 49 percent / CuI, TEA / Pd(CH₃CN)2Cl₂ / benzene

With copper(l) iodide; n-butyllithium; TEA; tetrabutyl ammonium fluoride; triethylamine; magnesium bromide; dichloro bis(acetonitrile) palladium(II); In tetrahydrofuran; dichloromethane; benzene;
DOI:10.1016/S0040-4039(01)80649-3

Reference yield:

: ((Z)-7,7-Diethoxy-hept-3-ene-1,5-diynyl)-dimethyl-(1,1,2-trimethyl-propyl)-silane

: 126629-14-9
4-[(3Z,9E)-7-(tert-Butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-8-methylene-deca-3,9-diene-1,5-diynyl]-[1,3]dioxol-2-one

Guidance literature:: Multi-step reaction with 5 steps

1: 85 percent / TFA/H₂O / CHCl₃ / Ambient temperature

2: 1.) n-BuLi, MgBr₂ / 1.) THF, -78 deg C

3: nBu₄NF / tetrahydrofuran / 0 °C

4: Et₃N / CH₂Cl₂ / 0 °C

5: 49 percent / CuI, TEA / Pd(CH₃CN)2Cl₂ / benzene

With copper(l) iodide; n-butyllithium; TEA; tetrabutyl ammonium fluoride; water; triethylamine; trifluoroacetic acid; magnesium bromide; dichloro bis(acetonitrile) palladium(II); In tetrahydrofuran; dichloromethane; chloroform; benzene;
DOI:10.1016/S0040-4039(01)80649-3