126629-13-8Relevant academic research and scientific papers
SYNTHESIS AND CRYSTALLOGRAPHIC ANALYSIS OF A BICYCLIC CORE RELATED TO THE ESPERAMICIN/CALICHEMICIN AGLYCONES
Schoenen, Frank J.,Porco, John A.,Schreiber, Stuart L.,VanDuyne, Gregory D.,Clardy, Jon
, p. 3765 - 3768 (1989)
The synthesis and crystallographic analysis of a bicyclic core related to the esperamicin/calichemicin aglycones is reported.A key reaction involves the skeletal rearrangement of a mesylate derived from a type II Diels-Alder cycloadduct.
