1-(4'-cyanobiphenyl-4-yl)-ferrocene

Base Information

Chemical Name:1-(4'-cyanobiphenyl-4-yl)-ferrocene
CAS No.:401845-44-1
Molecular Formula:C₂₃H₁₇FeN
Molecular Weight:363.242
Hs Code.:

Synonyms:1-(4'-cyanobiphenyl-4-yl)-ferrocene

Suppliers and Price of 1-(4'-cyanobiphenyl-4-yl)-ferrocene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-(4'-cyanobiphenyl-4-yl)-ferrocene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-(4'-cyanobiphenyl-4-yl)-ferrocene

There total 2 articles about 1-(4'-cyanobiphenyl-4-yl)-ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 1274-09-5
bis(ferrocenyl)mercury

: 57774-34-2
4′-iodo-[1,1′-biphenyl]-4-carbonitrile

: 401845-44-1
1-(4'-cyanobiphenyl-4-yl)-ferrocene

Guidance literature:: With NaI; bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; acetone; Fe-complex, ligand and NaI in THF and acetone were placed under Ar, mixt. heated to boiling, Pd-complex was added, refluxed for 1.5 h; filtered, evapd. in vac., column chromy. with benzene-hexane; elem. anal.;
DOI:10.1016/S0022-328X(01)00979-2

Reference yield: 41.0%

: 102-54-5,55404-68-7
ferrocene

: 661466-16-6
4'-cyano-4-biphenyldiazonium tetrafluoroborate

: 401845-44-1
1-(4'-cyanobiphenyl-4-yl)-ferrocene

Guidance literature:: In acetic acid; 1,2-dichloro-ethane; trifluoroacetic acid; portionwise addn. of diazonium salt to a soln. of ferrocene in a mixt. of dichloroethane, acetic acid, trifluoroacetic acid at 20°C during 15 min, stirring for 5 h, keeping at this temp. for 12 h; addn. of water and chloroform, sepn. of organic layer, extn. of aq. layer with chloroform, washing the soln. water, drying with MgSO4, evapn., chromy. (aluminum oxide, light petroleum followed with 5:1 benzene-light petroleum); elem. anal.;
DOI:10.1023/A:1023998420937

Reference yield: 35.0%

: 17746-05-3
undecanoyl chloride

: 401845-44-1
1-(4'-cyanobiphenyl-4-yl)-ferrocene

: 871732-73-9
1-(4'-cyanobiphenyl-4-yl)-1'-undecanoylferrocene

Guidance literature:: With AlCl₃; In dichloromethane; at 20°C under Ar atm.; mixt. of AlCl3, CH2Cl2 and C10H21COCl stirred for 1.5 h, then added dropwise to soln. of Fe-complex (ratio Fe-complex:C10H21COCl:AlCl3=1.0:1.1:2.0), stirred for 3 h, poured onto ice, concd. HCl and CHCl3 added; org. layer septd., washed (water), dried (MgSO4), filtered, solvent removed in vacuo, chromatographed (Al2O3, eluent 2:1 light petroleum:Et2O), recrystd. from light petroleum with small amt. of C6H6, then from acetone-hexane mixt.; elem. anal.;
DOI:10.1007/s11172-005-0053-6