tert-butyl(diphenyl)((4R,6R,8R,E)-4,6,8,10-tetramethylundec-2-enyloxy)silane

Base Information

Chemical Name:tert-butyl(diphenyl)((4R,6R,8R,E)-4,6,8,10-tetramethylundec-2-enyloxy)silane
CAS No.:1192344-65-2
Molecular Formula:C₃₁H₄₈OSi
Molecular Weight:464.807
Hs Code.:

Synonyms:tert-butyl(diphenyl)((4R,6R,8R,E)-4,6,8,10-tetramethylundec-2-enyloxy)silane

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Chemical Property of tert-butyl(diphenyl)((4R,6R,8R,E)-4,6,8,10-tetramethylundec-2-enyloxy)silane

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Technology Process of tert-butyl(diphenyl)((4R,6R,8R,E)-4,6,8,10-tetramethylundec-2-enyloxy)silane

There total 15 articles about tert-butyl(diphenyl)((4R,6R,8R,E)-4,6,8,10-tetramethylundec-2-enyloxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1192344-62-9
(2R,4R)-1-bromo-2,4,6-trimethylheptane

: 1184621-40-6
2-diphenylphosphanyl-benzoic acid (E)-(R)-1-(tert-butyl-diphenyl-silanyl-oxymethyl)-but-2-enyl ester

: 1192344-65-2
tert-butyl(diphenyl)((4R,6R,8R,E)-4,6,8,10-tetramethylundec-2-enyloxy)silane

Guidance literature:: (2R,4R)-1-bromo-2,4,6-trimethylheptane; With magnesium; In diethyl ether;

2-diphenylphosphanyl-benzoic acid (E)-(R)-1-(tert-butyl-diphenyl-silanyl-oxymethyl)-but-2-enyl ester; With copper(I) bromide dimethylsulfide complex; In diethyl ether;

Reference yield: 92.0%

: 1174752-28-3
2-diphenylphosphanyl-benzoic acid (E)-(S)-1-(tert-butyl-diphenyl-silanyl-oxymethyl)-but-2-enyl ester

: 1192344-62-9
(2R,4R)-1-bromo-2,4,6-trimethylheptane

: 1192344-65-2
tert-butyl(diphenyl)((4R,6R,8R,E)-4,6,8,10-tetramethylundec-2-enyloxy)silane

Guidance literature:: (2R,4R)-1-bromo-2,4,6-trimethylheptane; With magnesium; In diethyl ether; Inert atmosphere;

2-diphenylphosphanyl-benzoic acid (E)-(S)-1-(tert-butyl-diphenyl-silanyl-oxymethyl)-but-2-enyl ester; With copper(I) bromide dimethylsulfide complex; In diethyl ether; for 1.75h; stereospecific reaction; Inert atmosphere;
DOI:10.1021/ol901591t

Reference yield:

: 1192344-63-0
(R)-1-((2,4-dimethylpentyloxy)methyl)-4-methoxybenzene

: 1192344-65-2
tert-butyl(diphenyl)((4R,6R,8R,E)-4,6,8,10-tetramethylundec-2-enyloxy)silane

Guidance literature:: Multi-step reaction with 6 steps

1.1: hydrogen / palladium on activated charcoal

2.1: triphenylphosphine; N-Bromosuccinimide / dichloromethane / 0 - 20 °C

3.1: magnesium / diethyl ether

4.1: ozone / diethyl ether; pentane / -78 - 20 °C / Inert atmosphere

4.2: -78 - 20 °C

4.3: 2 h / 20 °C

5.1: triphenylphosphine; N-Bromosuccinimide

6.1: magnesium / diethyl ether

With N-Bromosuccinimide; hydrogen; ozone; magnesium; triphenylphosphine; palladium on activated charcoal; In diethyl ether; dichloromethane; pentane;