2-diphenylphosphanyl-benzoic acid (E)-(S)-1-(tert-butyl-diphenyl-silanyl-oxymethyl)-but-2-enyl ester

Base Information

Chemical Name:2-diphenylphosphanyl-benzoic acid (E)-(S)-1-(tert-butyl-diphenyl-silanyl-oxymethyl)-but-2-enyl ester
CAS No.:1174752-28-3
Molecular Formula:C₄₀H₄₁O₃PSi
Molecular Weight:628.823
Hs Code.:

Synonyms:2-diphenylphosphanyl-benzoic acid (E)-(S)-1-(tert-butyl-diphenyl-silanyl-oxymethyl)-but-2-enyl ester

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Chemical Property of 2-diphenylphosphanyl-benzoic acid (E)-(S)-1-(tert-butyl-diphenyl-silanyl-oxymethyl)-but-2-enyl ester

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Technology Process of 2-diphenylphosphanyl-benzoic acid (E)-(S)-1-(tert-butyl-diphenyl-silanyl-oxymethyl)-but-2-enyl ester

There total 4 articles about 2-diphenylphosphanyl-benzoic acid (E)-(S)-1-(tert-butyl-diphenyl-silanyl-oxymethyl)-but-2-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 17261-28-8
ortho-diphenylphosphinobenzoic acid

: 183508-07-8
(R,E)-1-(tert-butyldiphenylsilyloxy)pent-3-en-2-ol

: 1174752-28-3
2-diphenylphosphanyl-benzoic acid (E)-(S)-1-(tert-butyl-diphenyl-silanyl-oxymethyl)-but-2-enyl ester

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In diethyl ether; at -20 - 20 ℃; optical yield given as %ee; Inert atmosphere;
DOI:10.1002/chem.200901064

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 1174752-28-3
2-diphenylphosphanyl-benzoic acid (E)-(S)-1-(tert-butyl-diphenyl-silanyl-oxymethyl)-but-2-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1H-imidazole / dichloromethane

2: triphenylphosphine; di-isopropyl azodicarboxylate

With 1H-imidazole; di-isopropyl azodicarboxylate; triphenylphosphine; In dichloromethane; 2: Steglich esterification;

Reference yield:

: 853916-88-8
(-)-(E)-(R)-2-hydroxypent-3-enoic acid ethyl ester

: 1174752-28-3
2-diphenylphosphanyl-benzoic acid (E)-(S)-1-(tert-butyl-diphenyl-silanyl-oxymethyl)-but-2-enyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: lithium aluminium tetrahydride / diethyl ether

2: 1H-imidazole / dichloromethane

3: triphenylphosphine; di-isopropyl azodicarboxylate

With 1H-imidazole; lithium aluminium tetrahydride; di-isopropyl azodicarboxylate; triphenylphosphine; In diethyl ether; dichloromethane; 3: Steglich esterification;