3-(2',4'-di-O-acetyl-6'-azido-3'-O-benzyl-6'-deoxy-α-D-glucopyranosyl)-1-propene

Base Information

Chemical Name:3-(2',4'-di-O-acetyl-6'-azido-3'-O-benzyl-6'-deoxy-α-D-glucopyranosyl)-1-propene
CAS No.:848618-20-2
Molecular Formula:C₂₀H₂₅N₃O₆
Molecular Weight:403.435
Hs Code.:

Synonyms:3-(2',4'-di-O-acetyl-6'-azido-3'-O-benzyl-6'-deoxy-α-D-glucopyranosyl)-1-propene

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Chemical Property of 3-(2',4'-di-O-acetyl-6'-azido-3'-O-benzyl-6'-deoxy-α-D-glucopyranosyl)-1-propene

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Technology Process of 3-(2',4'-di-O-acetyl-6'-azido-3'-O-benzyl-6'-deoxy-α-D-glucopyranosyl)-1-propene

There total 1 articles about 3-(2',4'-di-O-acetyl-6'-azido-3'-O-benzyl-6'-deoxy-α-D-glucopyranosyl)-1-propene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 108-24-7
acetic anhydride

: 176257-50-4
3-(6'-azido-2',3',4'-tri-O-benzyl-6'-deoxy-α-D-glucopyranosyl)-1-propene

: 848618-20-2
3-(2',4'-di-O-acetyl-6'-azido-3'-O-benzyl-6'-deoxy-α-D-glucopyranosyl)-1-propene

Guidance literature:: 3-(6'-azido-2',3',4'-tri-O-benzyl-6'-deoxy-α-D-glucopyranosyl)-1-propene; With boron trichloride; In dichloromethane; at -78 ℃; for 2h;

acetic anhydride; In pyridine; at 20 ℃; for 15h;
DOI:10.1016/j.carres.2004.12.001

Reference yield:

: 848618-20-2
3-(2',4'-di-O-acetyl-6'-azido-3'-O-benzyl-6'-deoxy-α-D-glucopyranosyl)-1-propene

: (2R,3S,4R,5R,6R)-2-Allyl-6-azidomethyl-4-benzyloxy-tetrahydro-pyran-3,5-diol

Guidance literature:: With sodium methylate; In methanol;
DOI:10.1021/jo0502899

Reference yield:

: 848618-20-2
3-(2',4'-di-O-acetyl-6'-azido-3'-O-benzyl-6'-deoxy-α-D-glucopyranosyl)-1-propene

: 854377-19-8
3-(6'-azido-3'-O-benzyl-6'-deoxy-2',4'-di-O-methoxymethyl-α-D-glucopyranosyl)prop-1-ene

Guidance literature:: Multi-step reaction with 2 steps

1: MeONa / methanol

2: 11.12 g / NaH / dimethylformamide / 20 °C

With sodium methylate; sodium hydride; In methanol; N,N-dimethyl-formamide;
DOI:10.1021/jo0502899