1-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)propan-2-yl 5-chloro-2,4-dihydroxy benzoate

Base Information

Chemical Name:1-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)propan-2-yl 5-chloro-2,4-dihydroxy benzoate
CAS No.:854261-04-4
Molecular Formula:C₂₁H₂₄ClNO₁₁
Molecular Weight:501.875
Hs Code.:

Synonyms:1-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)propan-2-yl 5-chloro-2,4-dihydroxy benzoate

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Chemical Property of 1-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)propan-2-yl 5-chloro-2,4-dihydroxy benzoate

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Technology Process of 1-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)propan-2-yl 5-chloro-2,4-dihydroxy benzoate

There total 7 articles about 1-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)propan-2-yl 5-chloro-2,4-dihydroxy benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: 854261-03-3
1-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)propan-2-ol

: 67828-44-8
5-chloro-2,4-dihydroxy-benzoic acid

: 854261-04-4
1-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)propan-2-yl 5-chloro-2,4-dihydroxy benzoate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In tetrahydrofuran; N,N-dimethyl-formamide; at 50 ℃; for 12h;
DOI:10.1021/ol050580a

Reference yield:

: 854261-02-2
1-(2-methoxy-3,6-bis(methoxymethoxy)phenyl)propan-2-ol

: 854261-04-4
1-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)propan-2-yl 5-chloro-2,4-dihydroxy benzoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: NH₄NO₃; (CF₃CO)2O / acetonitrile / 0.25 h / 20 °C

1.2: LiOH / tetrahydrofuran; methanol; H₂O / 0.08 h

2.1: DMAP; DCC / dimethylformamide; tetrahydrofuran / 12 h / 50 °C

With ammonium nitrate; dmap; dicyclohexyl-carbodiimide; trifluoroacetic anhydride; In tetrahydrofuran; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo061054f

Reference yield:

: 131223-60-4
2-methoxy-1,4-bis-methoxymethoxy-benzene

: 854261-04-4
1-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)propan-2-yl 5-chloro-2,4-dihydroxy benzoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-BuLi

2.1: NH₄NO₃; (CF₃CO)2O / acetonitrile / 0.25 h / 20 °C

2.2: LiOH / tetrahydrofuran; methanol; H₂O / 0.08 h

3.1: DMAP; DCC / dimethylformamide; tetrahydrofuran / 12 h / 50 °C

With ammonium nitrate; dmap; n-butyllithium; dicyclohexyl-carbodiimide; trifluoroacetic anhydride; In tetrahydrofuran; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo061054f