1-(1,1-dimethylethyl)-1,1-dimethyl-N-(2-phenyl-1,4-pentadien-1-ylidene)silanamine

Base Information

Chemical Name:1-(1,1-dimethylethyl)-1,1-dimethyl-N-(2-phenyl-1,4-pentadien-1-ylidene)silanamine
CAS No.:960595-42-0
Molecular Formula:C₁₇H₂₅NSi
Molecular Weight:271.478
Hs Code.:

Synonyms:1-(1,1-dimethylethyl)-1,1-dimethyl-N-(2-phenyl-1,4-pentadien-1-ylidene)silanamine

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Chemical Property of 1-(1,1-dimethylethyl)-1,1-dimethyl-N-(2-phenyl-1,4-pentadien-1-ylidene)silanamine

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Technology Process of 1-(1,1-dimethylethyl)-1,1-dimethyl-N-(2-phenyl-1,4-pentadien-1-ylidene)silanamine

There total 2 articles about 1-(1,1-dimethylethyl)-1,1-dimethyl-N-(2-phenyl-1,4-pentadien-1-ylidene)silanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 5558-87-2
2-phenylpent-4-enenitrile

: 18162-48-6
tert-butyldimethylsilyl chloride

: 960595-42-0
1-(1,1-dimethylethyl)-1,1-dimethyl-N-(2-phenyl-1,4-pentadien-1-ylidene)silanamine

Guidance literature:: 2-phenylpent-4-enenitrile; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexanes; at -78 ℃; for 0.166667h; Inert atmosphere;

tert-butyldimethylsilyl chloride; In tetrahydrofuran; hexanes; at -78 - 20 ℃; for 3h; Inert atmosphere;
DOI:10.1021/ol201566u

Reference yield:

: 140-29-4
phenylacetonitrile

: 960595-42-0
1-(1,1-dimethylethyl)-1,1-dimethyl-N-(2-phenyl-1,4-pentadien-1-ylidene)silanamine

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium hexamethyldisilazane / tetrahydrofuran / 0.17 h / -78 °C / Inert atmosphere

1.2: 15 h / -78 - 20 °C / Inert atmosphere

2.1: n-butyllithium; diisopropylamine / tetrahydrofuran; hexanes / 0.17 h / -78 °C / Inert atmosphere

2.2: 3 h / -78 - 20 °C / Inert atmosphere

With n-butyllithium; diisopropylamine; lithium hexamethyldisilazane; In tetrahydrofuran; hexanes;
DOI:10.1021/ol201566u

Reference yield:

: 960595-42-0
1-(1,1-dimethylethyl)-1,1-dimethyl-N-(2-phenyl-1,4-pentadien-1-ylidene)silanamine

: 1550-89-6
N'-benzylidene-4-(trifluoromethyl)benzohydrazide

: C₂₆H₂₂F₃N₃O

: C₂₆H₂₂F₃N₃O

: 1264175-16-7
C₂₆H₂₂F₃N₃O

Guidance literature:: N'-benzylidene-4-(trifluoromethyl)benzohydrazide; With C₁₄H₂₂ClNO₂Si; In dichloromethane; for 15h; Inert atmosphere;

1-(1,1-dimethylethyl)-1,1-dimethyl-N-(2-phenyl-1,4-pentadien-1-ylidene)silanamine; In dichloromethane; at -20 ℃; for 3h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ol103096u