(S)-dimethyl(pent-1-en-3-yl)(phenyl)silane

Base Information

Chemical Name:(S)-dimethyl(pent-1-en-3-yl)(phenyl)silane
CAS No.:945684-67-3
Molecular Formula:C₁₃H₂₀Si
Molecular Weight:204.387
Hs Code.:

Synonyms:(S)-dimethyl(pent-1-en-3-yl)(phenyl)silane

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Chemical Property of (S)-dimethyl(pent-1-en-3-yl)(phenyl)silane

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Technology Process of (S)-dimethyl(pent-1-en-3-yl)(phenyl)silane

There total 6 articles about (S)-dimethyl(pent-1-en-3-yl)(phenyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 945684-60-6
(E)-3-(diethoxyphosphoryloxy)-1-(dimethylphenylsilyl)-1-propene

: 557-20-0
diethylzinc

: 945684-67-3
(S)-dimethyl(pent-1-en-3-yl)(phenyl)silane

Guidance literature:: With copper(I) trifluoromethanesulfonate benzene; chiral N-heterocyclic carbene-based silver catalyst; In tetrahydrofuran; at -15 ℃; for 24h;
DOI:10.1002/anie.200700841

Reference yield:

: 1192353-96-0
C₁₅H₂₅O₄PSi

: 557-20-0
diethylzinc

: 945684-67-3
(S)-dimethyl(pent-1-en-3-yl)(phenyl)silane

: 3-(dimethylphenylsilyl)-1-pentene

Guidance literature:: C₁₅H₂₅O₄PSi; With copper(II) choride dihydrate; (S)-((S)-1-benzylpyrrolidin-2-yl)(2-(diphenylphosphino)phenyl)methanol; In dichloromethane; at -78 ℃; Inert atmosphere;

diethylzinc; In hexane; dichloromethane; at -78 ℃; for 72h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1002/adsc.200900054

Reference yield:

: C₁₃H₂₂OSi

: 945684-67-3
(S)-dimethyl(pent-1-en-3-yl)(phenyl)silane

Guidance literature:: C₁₃H₂₂OSi; With ortho-nitrophenyl selenocyanate; tributylphosphine; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

With pyridine; dihydrogen peroxide; In dichloromethane; water; at 0 - 20 ℃; for 16.1667h;
DOI:10.1002/chem.201403849