945684-60-6

Basic information

• Product Name: (E)-3-(diethoxyphosphoryloxy)-1-(dimethylphenylsilyl)-1-propene
• Synonyms: (E)-3-(diethoxyphosphoryloxy)-1-(dimethylphenylsilyl)-1-propene
• CAS NO: 945684-60-6
• Molecular Weight: 328.42
• Mol File: 945684-60-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-3-(diethoxyphosphoryloxy)-1-(dimethylphenylsilyl)-1-propene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-(diethoxyphosphoryloxy)-1-(dimethylphenylsilyl)-1-propene(945684-60-6)
• EPA Substance Registry System: (E)-3-(diethoxyphosphoryloxy)-1-(dimethylphenylsilyl)-1-propene(945684-60-6)

Safety Data

• Hazardous Substances Data: 945684-60-6(Hazardous Substances Data)

Upstream product

• 101844-21-7 (E)-3-[(dimethyl)phenylsilyl]prop-2-en-1-ol 
• 814-49-3 diethyl chlorophosphate 

Downstream Products

• 103981-05-1 (S)-(-)-3-(dimethylphenylsilyl)-1-butene 
• 945684-67-3 (S)-dimethyl(pent-1-en-3-yl)(phenyl)silane 
• 945684-74-2 (R)-(-)-3-(dimethylphenylsilyl)-3-phenyl-1-propene 
• 945684-70-8 (S)-(+)-3-(dimethylphenylsilyl)-4-methyl-1-pentene 
• 945684-68-4 (S)-(+)-5-(dimethylphenylsilyl)-1-acetoxy-6-heptene 
• 945684-75-3 (R)-(-)-3-(dimethylphenylsilyl)-3-(4-methoxyphenyl)-1-propene 
• 945684-69-5 (S)-(+)-3-(dimethylphenylsilyl)-7-methyl-1-octene 
• 1353901-50-4 (S)-3-(dimethylphenylsilyl)-1,4,5-hexatriene 
• 1182847-29-5 (S)-hept-1-en-3-yldimethyl(phenyl)silane 
• 1005414-20-9 (R,E)-(9-tert-butoxynona-1,4-dien-3-yl)dimethyl(phenyl)silane 
• 1005414-45-8 (R,E)-dimethyl(phenyl)(undeca-1,4-dien-3-yl)silane 

Relevant articles and documents

Enantioselective synthesis of allylsilanes bearing tertiary and quaternary si-substituted carbons through Cu-catalyzed allylic alkylations with alkylzinc and arylzinc reagents

All sorts of allylsilanes including, for the first time, those that contain a Si-bonded quaternary carbon, were synthesized through efficient and highly enantioselective Cu-catalyzed asymmetric allylic alkylations. Reactions may involve dialkyl- as well as diarylzinc reagents and are promoted by various chiral N-heterocyclic carbene complexes.