N-benzylidene-2-benzylaniline

Base Information

• Chemical Name: N-benzylidene-2-benzylaniline
• CAS No.: 400060-04-0
• Molecular Formula: C₂₀H₁₇N
• Molecular Weight: 271.362
• Mol file: 400060-04-0.mol

Synonyms:N-benzylidene-2-benzylaniline

Chemical Property of N-benzylidene-2-benzylaniline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of N-benzylidene-2-benzylaniline

There total 1 articles about N-benzylidene-2-benzylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

2-benzylaniline (28059-64-5) + benzaldehyde (100-52-7) → N-benzylidene-2-benzylaniline (400060-04-0)

Guidance literature:

In benzene; at 40 ℃; for 2h;

DOI:10.1002/jhet.5570450331

Reference yield: 74.0%

N-benzylidene-2-benzylaniline (400060-04-0) + chloroform (67-66-3,8013-54-5) → 1-(2-benzylphenyl)-2,2-dichloro-3-phenylaziridine (1309881-96-6)

Guidance literature:

With N-benzyl-N,N,N-triethylammonium chloride; potassium hydroxide; at 19 - 21 ℃; for 3h;

DOI:10.1039/c1ob05081h

Reference yield:

N-benzylidene-2-benzylaniline (400060-04-0) → trans-1-phenyl-7,11b-dihydro-1H-azirino[1,2-a]dibenzo[c,f]azepine

Guidance literature:

Multi-step reaction with 3 steps

1: N-benzyl-N,N,N-triethylammonium chloride; potassium hydroxide / 3 h / 19 - 21 °C

2: tin(IV) chloride / nitromethane / 1.5 h / 20 - 35 °C

3: lithium aluminium tetrahydride / diethyl ether / 3 h / Reflux

With lithium aluminium tetrahydride; N-benzyl-N,N,N-triethylammonium chloride; tin(IV) chloride; potassium hydroxide; In diethyl ether; nitromethane; 2: Friedel Crafts acylation;

DOI:10.1039/c1ob05081h

upstream raw materials:

2-benzylaniline

benzaldehyde

Downstream raw materials:

dimethyl 3-phenyl-9H-dibenzo[c,f]pyrrolo[1,2-a]azepine-1,2-dicarboxylate

1-(2-benzylphenyl)-2,2-dichloro-3-phenylaziridine