1D-6-O-(2-azido-3,4-di-O-benzyl-2,6-dideoxy-α-D-glucopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

Base Information

Chemical Name:1D-6-O-(2-azido-3,4-di-O-benzyl-2,6-dideoxy-α-D-glucopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol
CAS No.:714957-36-5
Molecular Formula:C₆₂H₆₅N₃O₁₀
Molecular Weight:1012.21
Hs Code.:

Synonyms:1D-6-O-(2-azido-3,4-di-O-benzyl-2,6-dideoxy-α-D-glucopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

Suppliers and Price of 1D-6-O-(2-azido-3,4-di-O-benzyl-2,6-dideoxy-α-D-glucopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1D-6-O-(2-azido-3,4-di-O-benzyl-2,6-dideoxy-α-D-glucopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1D-6-O-(2-azido-3,4-di-O-benzyl-2,6-dideoxy-α-D-glucopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

There total 8 articles about 1D-6-O-(2-azido-3,4-di-O-benzyl-2,6-dideoxy-α-D-glucopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 129261-63-8
(+)-1D-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

: 324739-92-6
2-azido-3,4-di-O-benzyl-2,6-dideoxy-D-glucopyranosyl fluoride

: 714957-36-5
1D-6-O-(2-azido-3,4-di-O-benzyl-2,6-dideoxy-α-D-glucopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

Guidance literature:: With silver perchlorate; tetramethylurea; zirconocene dichloride; In 1,4-dioxane; toluene; for 22h;
DOI:10.1016/j.carres.2004.02.026

Reference yield:

: 100-39-0
benzyl bromide

: 714957-36-5
1D-6-O-(2-azido-3,4-di-O-benzyl-2,6-dideoxy-α-D-glucopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

Guidance literature:: Multi-step reaction with 4 steps

1: 1.2 g / NaH / dimethylformamide / 0.5 h / 20 °C

2: 42 percent / HCl / acetic acid; H₂O / 48 h / 90 - 100 °C

3: 81 percent / DAST / 1,2-dichloro-ethane / 20 °C

4: 50 percent / 1,1,3,3-tetramethylurea; AgClO₄ / Cp₂ZrCl₂ / toluene; dioxane / 22 h

With hydrogenchloride; silver perchlorate; sodium hydride; 4,4'-diaminostilbene-2,2'-disulfonic acid; tetramethylurea; zirconocene dichloride; In 1,4-dioxane; water; acetic acid; 1,2-dichloro-ethane; N,N-dimethyl-formamide; toluene;
DOI:10.1016/j.carres.2004.02.026

Reference yield:

: 197577-13-2
(2S,3S,4aR,5R,7S,8S,8aR)-2,3,7-Trimethoxy-2,3,5-trimethyl-hexahydro-pyrano[3,4-b][1,4]dioxin-8-ol

: 714957-36-5
1D-6-O-(2-azido-3,4-di-O-benzyl-2,6-dideoxy-α-D-glucopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

Guidance literature:: Multi-step reaction with 7 steps

1: 0.82 g / pyridine; CH₂Cl₂ / 2 h / 10 °C

2: 0.34 g / NaN₃ / dimethylformamide / 75 °C

3: 0.79 g / trifluoroacetic acid; H₂O / 0.03 h / 20 °C

4: 1.2 g / NaH / dimethylformamide / 0.5 h / 20 °C

5: 42 percent / HCl / acetic acid; H₂O / 48 h / 90 - 100 °C

6: 81 percent / DAST / 1,2-dichloro-ethane / 20 °C

7: 50 percent / 1,1,3,3-tetramethylurea; AgClO₄ / Cp₂ZrCl₂ / toluene; dioxane / 22 h

With pyridine; hydrogenchloride; sodium azide; dichloromethane; silver perchlorate; sodium hydride; 4,4'-diaminostilbene-2,2'-disulfonic acid; tetramethylurea; zirconocene dichloride; In 1,4-dioxane; water; acetic acid; 1,2-dichloro-ethane; N,N-dimethyl-formamide; toluene; trifluoroacetic acid;
DOI:10.1016/j.carres.2004.02.026