tert-butyl-{4-[2-(3-chloro-propyl)-[1,3]dithian-2-yl]-butoxy}-diphenyl-silane

Base Information

Chemical Name:tert-butyl-{4-[2-(3-chloro-propyl)-[1,3]dithian-2-yl]-butoxy}-diphenyl-silane
CAS No.:405915-62-0
Molecular Formula:C₂₇H₃₉ClOS₂Si
Molecular Weight:507.277
Hs Code.:

<i>tert</i>-butyl-{4-[2-(3-chloro-propyl)-[1,3]dithian-2-yl]-butoxy}-diphenyl-silane

Synonyms:tert-butyl-{4-[2-(3-chloro-propyl)-[1,3]dithian-2-yl]-butoxy}-diphenyl-silane

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Chemical Property of tert-butyl-{4-[2-(3-chloro-propyl)-[1,3]dithian-2-yl]-butoxy}-diphenyl-silane

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Technology Process of tert-butyl-{4-[2-(3-chloro-propyl)-[1,3]dithian-2-yl]-butoxy}-diphenyl-silane

There total 5 articles about tert-butyl-{4-[2-(3-chloro-propyl)-[1,3]dithian-2-yl]-butoxy}-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 109-70-6
1.3-chlorobromopropane

: 405914-97-8
2-(4'-(tert-butyldiphenylsilyloxy)butane)-1,3-dithiane

: 405915-62-0
tert-butyl-{4-[2-(3-chloro-propyl)-[1,3]dithian-2-yl]-butoxy}-diphenyl-silane

Guidance literature:: 2-(4'-(tert-butyldiphenylsilyloxy)butane)-1,3-dithiane; With n-butyllithium; In tetrahydrofuran; at -78 - 0 ℃; for 1h;

1.3-chlorobromopropane; In tetrahydrofuran; at -78 - 20 ℃; for 3h; Further stages.;
DOI:10.1021/ol0172368

Reference yield:

: 111-29-5
1 ,5-pentanediol

: 405915-62-0
tert-butyl-{4-[2-(3-chloro-propyl)-[1,3]dithian-2-yl]-butoxy}-diphenyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1.1: 86.3 percent / imidazole / dimethylformamide / 18 h / 20 °C

2.1: 88 percent / PCC; Celite; NaOAc / CH₂Cl₂ / 2 h

3.1: 96 percent / MgBr₂*Et₂O / diethyl ether / 1 h / 20 °C

4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C

4.2: 96 percent / tetrahydrofuran / 3 h / -78 - 20 °C

With 1H-imidazole; n-butyllithium; Celite; sodium acetate; pyridinium chlorochromate; magnesium bromide; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol0172368

Reference yield:

: 131216-47-2
5-(tert-butyldiphenylsilyloxy)pentanal

: 405915-62-0
tert-butyl-{4-[2-(3-chloro-propyl)-[1,3]dithian-2-yl]-butoxy}-diphenyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1.1: 96 percent / MgBr₂*Et₂O / diethyl ether / 1 h / 20 °C

2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C

2.2: 96 percent / tetrahydrofuran / 3 h / -78 - 20 °C

With n-butyllithium; magnesium bromide; In tetrahydrofuran; diethyl ether;
DOI:10.1021/ol0172368