methyl 6-O-(tert-butyldiphenylsilyl)-4-deoxy-2,3-di-O-methyl-4-methylene-α-D-xylo-hexopyranoside

Base Information

Chemical Name:methyl 6-O-(tert-butyldiphenylsilyl)-4-deoxy-2,3-di-O-methyl-4-methylene-α-D-xylo-hexopyranoside
CAS No.:1254811-91-0
Molecular Formula:C₂₆H₃₆O₅Si
Molecular Weight:456.654
Hs Code.:

Synonyms:methyl 6-O-(tert-butyldiphenylsilyl)-4-deoxy-2,3-di-O-methyl-4-methylene-α-D-xylo-hexopyranoside

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Chemical Property of methyl 6-O-(tert-butyldiphenylsilyl)-4-deoxy-2,3-di-O-methyl-4-methylene-α-D-xylo-hexopyranoside

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Technology Process of methyl 6-O-(tert-butyldiphenylsilyl)-4-deoxy-2,3-di-O-methyl-4-methylene-α-D-xylo-hexopyranoside

There total 1 articles about methyl 6-O-(tert-butyldiphenylsilyl)-4-deoxy-2,3-di-O-methyl-4-methylene-α-D-xylo-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 938081-98-2
methyl 6-O-[tert-butyl(diphenyl)silyl]-2,3-di-O-methyl-α-D-xylo-hexopyranosid-4-ulose

: 1779-49-3
Methyltriphenylphosphonium bromide

: 1254811-91-0
methyl 6-O-(tert-butyldiphenylsilyl)-4-deoxy-2,3-di-O-methyl-4-methylene-α-D-xylo-hexopyranoside

Guidance literature:: Methyltriphenylphosphonium bromide; With n-butyllithium; In tetrahydrofuran; at -78 - 0 ℃; for 0.5h; Inert atmosphere;

methyl 6-O-[tert-butyl(diphenyl)silyl]-2,3-di-O-methyl-α-D-xylo-hexopyranosid-4-ulose; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1002/ejoc.201000470

Reference yield: 30.0%

: 1254811-91-0
methyl 6-O-(tert-butyldiphenylsilyl)-4-deoxy-2,3-di-O-methyl-4-methylene-α-D-xylo-hexopyranoside

: 1254811-95-4
methyl 6-O-(tert-butyldiphenylsilyl)-4-deoxy-4-hydroxymethyl-2,3-di-O-methyl-β-D-glucopyranoside

: 1254811-93-2
methyl 6-O-(tert-butyldiphenylsilyl)-4-deoxy-4-hydroxymethyl-2,3-di-O-methyl-α-D-glucopyranoside

Guidance literature:: methyl 6-O-(tert-butyldiphenylsilyl)-4-deoxy-2,3-di-O-methyl-4-methylene-α-D-xylo-hexopyranoside; With 9-bora-bicyclo[3.3.1]nonane; In tetrahydrofuran; for 4h; Inert atmosphere; Reflux;

With dihydrogen peroxide; sodium hydroxide; In tetrahydrofuran; water; at 0 ℃; for 0.5h; Inert atmosphere;
DOI:10.1002/ejoc.201000470