(3aS,4R,6S,7R,7aR)-6-(2,6-Dimethyl-phenylsulfanyl)-4-(1-methoxy-1-methyl-ethoxymethyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol

Base Information

Chemical Name:(3aS,4R,6S,7R,7aR)-6-(2,6-Dimethyl-phenylsulfanyl)-4-(1-methoxy-1-methyl-ethoxymethyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol
CAS No.:911684-30-5
Molecular Formula:C₂₁H₃₂O₆S
Molecular Weight:412.547
Hs Code.:

Synonyms:(3aS,4R,6S,7R,7aR)-6-(2,6-Dimethyl-phenylsulfanyl)-4-(1-methoxy-1-methyl-ethoxymethyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol

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Chemical Property of (3aS,4R,6S,7R,7aR)-6-(2,6-Dimethyl-phenylsulfanyl)-4-(1-methoxy-1-methyl-ethoxymethyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol

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Technology Process of (3aS,4R,6S,7R,7aR)-6-(2,6-Dimethyl-phenylsulfanyl)-4-(1-methoxy-1-methyl-ethoxymethyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol

There total 4 articles about (3aS,4R,6S,7R,7aR)-6-(2,6-Dimethyl-phenylsulfanyl)-4-(1-methoxy-1-methyl-ethoxymethyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 911684-29-2
2,6-dimethylphenyl 1-thio-β-D-galactopyranoside

: 77-76-9
2,2-dimethoxy-propane

: 911684-30-5
(3aS,4R,6S,7R,7aR)-6-(2,6-Dimethyl-phenylsulfanyl)-4-(1-methoxy-1-methyl-ethoxymethyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol

Guidance literature:: camphor-10-sulfonic acid; at 20 ℃;
DOI:10.1021/ja063247q

Reference yield:

: 911684-14-5
2,6-dimethylphenyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-galactopyranoside

: 911684-30-5
(3aS,4R,6S,7R,7aR)-6-(2,6-Dimethyl-phenylsulfanyl)-4-(1-methoxy-1-methyl-ethoxymethyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / NaOMe / methanol / 2 h / 20 °C

2: 58 percent / camphorsulfonic acid / 20 °C

With sodium methylate; camphor-10-sulfonic acid; In methanol;
DOI:10.1021/ja063247q

Reference yield:

: 118-72-9
2,6-dimethylbenzene-1-thiol

: 911684-30-5
(3aS,4R,6S,7R,7aR)-6-(2,6-Dimethyl-phenylsulfanyl)-4-(1-methoxy-1-methyl-ethoxymethyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 56 percent / BF₃EtO₂ / CH₂Cl₂; toluene / 4 h / 50 °C

2: 100 percent / NaOMe / methanol / 2 h / 20 °C

3: 58 percent / camphorsulfonic acid / 20 °C

With boron trifluoride diethyl etherate; sodium methylate; camphor-10-sulfonic acid; In methanol; dichloromethane; toluene;
DOI:10.1021/ja063247q