Technology Process of C36H42Si2
There total 3 articles about C36H42Si2 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C52H50I4Si2;
With
tert.-butyl lithium;
In
tetrahydrofuran; pentane;
at -78 ℃;
for 0.5h;
Inert atmosphere;
In
tetrahydrofuran; pentane;
at 20 ℃;
for 1h;
Inert atmosphere;
With
water;
In
tetrahydrofuran; hexane;
Inert atmosphere;
DOI:10.1016/j.tetlet.2009.01.152
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: zirconocene dichloride; n-butyllithium / toluene; pentane / -78 - 50 °C / Inert atmosphere
1.2: 1 h / 50 °C / Inert atmosphere
1.3: 0 - 20 °C / Inert atmosphere
2.1: tert.-butyl lithium / diethyl ether; pentane / -78 °C / Inert atmosphere; Reflux
2.2: -78 - 20 °C / Inert atmosphere
With
n-butyllithium; zirconocene dichloride; tert.-butyl lithium;
In
diethyl ether; toluene; pentane;
DOI:10.1002/asia.200900287
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: zirconocene dichloride; n-butyllithium / toluene; pentane / -78 - 50 °C / Inert atmosphere
1.2: 1 h / 50 °C / Inert atmosphere
1.3: 0 - 20 °C / Inert atmosphere
2.1: tert.-butyl lithium / diethyl ether; pentane / -78 °C / Inert atmosphere; Reflux
2.2: -78 - 20 °C / Inert atmosphere
With
n-butyllithium; zirconocene dichloride; tert.-butyl lithium;
In
diethyl ether; toluene; pentane;
DOI:10.1002/asia.200900287
