trans-Fe(CO)3(PPh₂CH=CH₂)2

Base Information

Chemical Name:trans-Fe(CO)3(PPh₂CH=CH₂)2
CAS No.:87137-61-9
Molecular Formula:C₃₁H₂₆FeO₃P₂
Molecular Weight:564.34
Hs Code.:

trans-Fe(CO)3(PPh<sub>2</sub>CH=CH<sub>2</sub>)2

Synonyms:trans-Fe(CO)3(PPh₂CH=CH₂)2

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Chemical Property of trans-Fe(CO)3(PPh₂CH=CH₂)2

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Technology Process of trans-Fe(CO)3(PPh₂CH=CH₂)2

There total 2 articles about trans-Fe(CO)3(PPh₂CH=CH₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 16940-66-2
sodium tetrahydroborate

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 2155-96-6
Diphenylvinylphosphine

: 87137-61-9
trans-Fe(CO)3(PPh₂CH=CH₂)2

: 36870-06-1
trans-Fe(CO)3(PPh₂Et)2

: trans-Fe(CO)3(PPh₂CH₂CH₃)(PPh₂CH=CH₂)

Guidance literature:: In butan-1-ol; byproducts: H2; (N2); addn. of Fe(CO)5 to a stirred mixt. of PPh2CH=CH2 and NaBH4 and reflux the mixt. after gas evolution for 2 h; then cooling the mixt. to room temp. and placing it in a freezer at 5°C for 12 h;; filtration and washing (CH3OH) of the resulting ppt.; treatment with CH2Cl2 and filtration again; collecting of the product by filtration after addn. of CH3OH and standing of the mixt. in a freezer for several hours;;
DOI:10.1021/om00102a006

Reference yield: 55.0%

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 2155-96-6
Diphenylvinylphosphine

: 87137-61-9
trans-Fe(CO)3(PPh₂CH=CH₂)2

Guidance literature:: With NaBH₄; In tetrahydrofuran; elem. anal.;

Reference yield: 79.0%

: 87137-61-9
trans-Fe(CO)3(PPh₂CH=CH₂)2

: 829-85-6
diphenylphosphane

: 87137-63-1
trans-Fe(CO)4(η1-PPh2CH2CH2PPh2)2

Guidance literature:: With potassium tert-butoxide; In tetrahydrofuran; KOBu-t was added to a 1:2 ratio mixture of complex and PPh2H, refluxed for 2 h, under N2; evapn., a residue was dissolved in a minimum of CH2Cl2, pptn. with MeOHat 5°C for 12 h; elem. anal.;