chloro(pyridine)bis(2,3-dimesitylglyoxal dioximato-κ4N)cobalt(III)

Base Information

Chemical Name:chloro(pyridine)bis(2,3-dimesitylglyoxal dioximato-κ4N)cobalt(III)
CAS No.:130274-21-4
Molecular Formula:C₄₅H₅₁ClCoN₅O₄
Molecular Weight:820.377
Hs Code.:

Synonyms:chloro(pyridine)bis(2,3-dimesitylglyoxal dioximato-κ4N)cobalt(III)

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Chemical Property of chloro(pyridine)bis(2,3-dimesitylglyoxal dioximato-κ4N)cobalt(III)

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Technology Process of chloro(pyridine)bis(2,3-dimesitylglyoxal dioximato-κ4N)cobalt(III)

There total 1 articles about chloro(pyridine)bis(2,3-dimesitylglyoxal dioximato-κ4N)cobalt(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: cobalt(II) chloride hexahydrate

: 16031-62-2
dimesitylglyoxal dioxime

: 130274-21-4
chloro(pyridine)bis(2,3-dimesitylglyoxal dioximato-κ4N)cobalt(III)

Guidance literature:: With pyridine; triethylamine; In tetrahydrofuran; ethanol; under N2, addn. of ligand, pyridine and NEt3 in THF to a hot soln. of CoCl2*6H2O in ethanol, allowed to cool to room temp., stream of air bubbled through it for 1 h; volume reduced, cooled in a refrigerator overnight, recrystn. (CHCl3); elem. anal.;

Reference yield: 90.0%

: 130274-21-4
chloro(pyridine)bis(2,3-dimesitylglyoxal dioximato-κ4N)cobalt(III)

: 74-88-4
methyl iodide

: 849437-38-3
[MeCo(dimesitylglyoxime(-1H))2(pyridine)]

Guidance literature:: With NaBH₄; NaOH; In ethanol; N2 was bubbled through stirred soln. of Co complex in ethanol at -10°C for 10 min; few drops of aq. NaOH was added; aq. soln. of NaBH4 (10 equiv.) was added; soln. of MeI in ethanol was added; stirred at 0°C for 1 h; poured into H2O/few drops of pyridine; filtered; washed (H2O); dried; chromd. (silica gel, CH2Cl2/petroleum ether, 5/1, CH2Cl2); elem. anal.;
DOI:10.1021/om049096m

Reference yield: 72.0%

: sodium azide

: 130274-21-4
chloro(pyridine)bis(2,3-dimesitylglyoxal dioximato-κ4N)cobalt(III)

: 849437-45-2
[(N₃)Co(dimesitylglyoxime(-1H))2(pyridine)]

Guidance literature:: In methanol; water; soln. of Na salt was added to refluxing suspn. of Co complex in methanol; mixt. was refluxed for 4 h; evapd.; dissolved in CHCl3; chromd. (silica gel, 5-10% CHCl3/ethyl acetate); elem. anal.;
DOI:10.1021/om049096m