2-(4-dodecyl-phenyl)-4,4,5,5-tetramethyl-[1,3,2]-dioxaborolane

Base Information

• Chemical Name: 2-(4-dodecyl-phenyl)-4,4,5,5-tetramethyl-[1,3,2]-dioxaborolane
• CAS No.: 1398398-12-3
• Molecular Formula: C₂₄H₄₁BO₂
• Molecular Weight: 372.399
• Mol file: 1398398-12-3.mol

Synonyms:2-(4-dodecyl-phenyl)-4,4,5,5-tetramethyl-[1,3,2]-dioxaborolane

Chemical Property of 2-(4-dodecyl-phenyl)-4,4,5,5-tetramethyl-[1,3,2]-dioxaborolane

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(4-dodecyl-phenyl)-4,4,5,5-tetramethyl-[1,3,2]-dioxaborolane

There total 2 articles about 2-(4-dodecyl-phenyl)-4,4,5,5-tetramethyl-[1,3,2]-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

1-bromo-4-dodecylbenzene (126930-72-1) + bis(pinacol)diborane (73183-34-3) → 2-(4-dodecyl-phenyl)-4,4,5,5-tetramethyl-[1,3,2]-dioxaborolane (1398398-12-3)

Guidance literature:

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate; In 1,4-dioxane; at 100 ℃; for 12h;

DOI:10.1002/asia.201500450

Reference yield: 65.0%

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (61676-62-8) + 1-bromo-4-dodecylbenzene (126930-72-1) → 2-(4-dodecyl-phenyl)-4,4,5,5-tetramethyl-[1,3,2]-dioxaborolane (1398398-12-3)

Guidance literature:

1-bromo-4-dodecylbenzene; With n-butyllithium; In tetrahydrofuran; Inert atmosphere; Schlenk technique;

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; In tetrahydrofuran; Inert atmosphere;

DOI:10.1039/c3cc42114g

Reference yield: 86.0%

2-(4-dodecyl-phenyl)-4,4,5,5-tetramethyl-[1,3,2]-dioxaborolane (1398398-12-3) + 2,6-dibromodithieno[3,2-b:2',3'-d]thiophene (67061-69-2) → 2,6-bis(4-dodecylphenyl)-dithieno[3,2-b:2',3'-d]thiophene (1446140-70-0)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In tetrahydrofuran; water; at 60 ℃; for 24h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c3cc42114g

upstream raw materials:

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

1-bromo-4-dodecylbenzene

bis(pinacol)diborane

Downstream raw materials:

2,6-bis(4-dodecylphenyl)-dithieno[3,2-b:2',3'-d]thiophene

C₆₆H₉₆N₂O₂S₂