Cupriethylene diamine

Base Information

• Chemical Name: Cupriethylene diamine
• CAS No.: 13426-91-0
• Deprecated CAS: 45650-15-5
• Molecular Formula: C₄H₁₆CuN₄
• Molecular Weight: 183.744
• European Community (EC) Number: 603-806-6
• UN Number: 1761 (Cupriethylenediamine, solution),1761
• Mol file: 13426-91-0.mol

Synonyms:Cupriethylene diamine;CUPRIETHYLENEDIAMINE;Copper(2+), bis(ethylenediamine)-, ion;Bis(ethylenediamine)copper ion;Bis(ethylenediamine)copper(2+);Bis(ethylenediamine)copper(2+) ion;13426-91-0;NIP4I4LVCC;Cupriethylenediamine, bis(ethylenediamine)-, ion;Copper(2+), bis(1,2-ethanediamine-N,N')-, (SP-4-1)-;Koplex aquatic herbicide;UNII-NIP4I4LVCC;Bis(1,2-ethanediamine-N,N')copper(2+);HSDB 2767;UN1761;Copper(2++), bis(1,2-ethanediamine-N,N')-;copper;2-azanidylethylazanide;Copper(2+), bis(1,2-ethanediamine-kappaN,kappaN')-, (SP-4-1)-

Chemical Property of Cupriethylene diamine

Chemical Property:

• Vapor Pressure: 15.8mmHg at 25°C
• Boiling Point: 119.7°Cat760mmHg
• Flash Point: 33.9°C
• PSA: 104.08000
• Density: g/cm³
• LogP: 0.60630
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 179.035794
• Heavy Atom Count: 9
• Complexity: 20.5

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Organic Compounds, Metal Salts
• Canonical SMILES: C(C[NH-])[NH-].C(C[NH-])[NH-].[Cu+2]

Technology Process of Cupriethylene diamine

There total 11 articles about Cupriethylene diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

bis(1,1,2,2,-tetrafluoro-5-phenyl-3,5-heptanedionato)copper + ethylenediamine (107-15-3,85404-18-8) → [Cu(ethylenediamine)2](2+) (13426-91-0,220026-26-6) + bis(1,1,2,2-terafluoro-5-phenyl-3,5-heptanedionato)copper*2(ethylenediamine)

Guidance literature:

In chloroform; stirring of Cu-compd. in CHCl3 with 10-fold excess of ethylenediamine;; ppt. was filtered and washed with water to remove (Cu(NH2CH2CH2NH2)2)(2+); dried under vac., washed with benzene;;

DOI:10.1007/BF00960416

Reference yield:

{Cuen2}Cl2 → [Cu(ethylenediamine)2](2+) (13426-91-0,220026-26-6)

Guidance literature:

With water; In methanol; in methanol;;

Reference yield:

(imidodiacetate)(ethylenediamine)copper(II) (26881-92-5,143279-81-6) → [Cu(ethylenediamine)2](2+) (13426-91-0,220026-26-6) + (imidodiacetate)2copper(II)(2-)

Guidance literature:

In not given; at 30°C;; in soln.;;

DOI:10.1021/ja01563a008

upstream raw materials:

(imidodiacetate)(ethylenediamine)copper(II)

[Cu(ethylenediamine)(ethylenediaminetetraacetato)]^(2-)

ethylenediamine

Downstream raw materials:

bis(2,9-dimethyl-1,10-phenathroline) copper(I)

Cu(ethylenediamine)2(7,7,8,8-tetracyanoquinodimethanide)2

Refernces

• 1、 Diaz, Guillermo,Bustos, Carlos,Shepherd, Rex E.. "". . p. 23 - 26. Retrieved 1987.
• 2、 Bennett, W. E.. "". . p. 1290 - 1293. Retrieved 1957.
• 3、 Bernhardt, Paul V.,Comba, Peter,Hambley, Trevor W.,Massoud, Salah S.,Stebler, Sandra. "Determination of solution structures of binuclear copper(II) complexes". . p. 2644 - 2651. Retrieved 2008/10/08.