[(P(C₆H₅)3)2N][Rh(CO)2ON(3,4-Cl₂(C₆H₃))C(O)O]

Base Information

• Chemical Name: [(P(C₆H₅)3)2N][Rh(CO)2ON(3,4-Cl₂(C₆H₃))C(O)O]
• CAS No.: 145312-01-2
• Molecular Formula: C₉H₃Cl₂NO₅Rh*C₃₆H₃₀NP₂
• Molecular Weight: 917.526
• Mol file: 145312-01-2.mol

Synonyms:[(P(C₆H₅)3)2N][Rh(CO)2ON(3,4-Cl₂(C₆H₃))C(O)O]

Chemical Property of [(P(C₆H₅)3)2N][Rh(CO)2ON(3,4-Cl₂(C₆H₃))C(O)O]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(P(C₆H₅)3)2N][Rh(CO)2ON(3,4-Cl₂(C₆H₃))C(O)O]

There total 2 articles about [(P(C₆H₅)3)2N][Rh(CO)2ON(3,4-Cl₂(C₆H₃))C(O)O] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

[bis(triphenylphosphoranylidene)iminium][Rh(CO)4] (74364-66-2) + 3,4-dichloronitrobenzene (99-54-7) → [(P(C6H5)3)2N][Rh(CO)2ON(3,4-Cl2(C6H3))C(O)O] (145312-01-2)

Guidance literature:

With carbon monoxide; In tetrahydrofuran; 3,4-Cl2(C6H3)NO2 added to soln. of (PPN)(Rh(CO)4) in THF at -78°Cunder CO atm, suspn. allowed to warm to room temp. under stirring withi n 30 min, IR monitoring; flask evacuated and filled with N2, n-hexane added, solid filtered off, washed with n-hexane and dried under vac.; elem. anal.;

DOI:10.1016/S0022-328X(99)00502-1

Reference yield: 74.0%

[bis(triphenylphosphoranylidene)iminium][Rh(CO)4] (74364-66-2) + 3,4-dichloronitrobenzene (99-54-7) → [(C6H5)3PNP(C6H5)3](1+)*[Rh(CO)2(CO2NOC6H3Cl2)](1-)=[(C6H5)3PNP(C6H5)3][Rh(CO)2(CO2NOC6H3Cl2)] (145312-01-2)

Guidance literature:

With CO; In tetrahydrofuran; soln. of Rh-complex in THF is saturated with CO, slow addn. of Cl2C6H3NO2, stirring for 10 min; addn. of hexane, vac. drying, elem. anal.;

Reference yield:

[(P(C6H5)3)2N][Rh(CO)2ON(3,4-Cl2(C6H3))C(O)O] (145312-01-2) → [bis(triphenylphosphoranylidene)iminium][Rh(CO)4] (74364-66-2)

Guidance literature:

With carbon monoxide; aniline; In tetrahydrofuran; byproducts: 3,4-Cl2(C6H3)NHCONHC6H5, C6H5NHCONHC6H5; aniline added to soln. of Rh complex at room temp. under CO atm, soln. stirred for 4 h; detected by IR spectroscopy;

DOI:10.1016/S0022-328X(99)00502-1

upstream raw materials:

[bis(triphenylphosphoranylidene)iminium][Rh(CO)4]

3,4-dichloronitrobenzene

Downstream raw materials:

[bis(triphenylphosphoranylidene)iminium][Rh(CO)4]

{(μ-nitrido)bis(triphenylphosphorus)}{Rh(CO)2Cl2}

[(P(C₆H₅)3)2N]⁽¹⁺⁾*[Rh(CO)2(CH₃COO)2]^(1-)=[(P(C₆H₅)3)2N][Rh(CO)2(CH₃COO)2]

[(P(C₆H₅)3)2N]⁽¹⁺⁾*[Rh(CO)2((CH₃)3CCOO)2]^(1-) = [(P(C₆H₅)3)2N][Rh(CO)2(C₄H₉COO)2]