2-{Hydroxy-[4-(1-hydroxy-2-methoxycarbonyl-allyl)-phenyl]-methyl}-acrylic acid methyl ester

Base Information

• Chemical Name: 2-{Hydroxy-[4-(1-hydroxy-2-methoxycarbonyl-allyl)-phenyl]-methyl}-acrylic acid methyl ester
• CAS No.: 127870-75-1
• Molecular Formula: C₁₆H₁₈O₆
• Molecular Weight: 306.315
• Mol file: 127870-75-1.mol

Synonyms:2-{Hydroxy-[4-(1-hydroxy-2-methoxycarbonyl-allyl)-phenyl]-methyl}-acrylic acid methyl ester

Chemical Property of 2-{Hydroxy-[4-(1-hydroxy-2-methoxycarbonyl-allyl)-phenyl]-methyl}-acrylic acid methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-{Hydroxy-[4-(1-hydroxy-2-methoxycarbonyl-allyl)-phenyl]-methyl}-acrylic acid methyl ester

There total 1 articles about 2-{Hydroxy-[4-(1-hydroxy-2-methoxycarbonyl-allyl)-phenyl]-methyl}-acrylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

terephthalaldehyde, (623-27-8) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → 2-{Hydroxy-[4-(1-hydroxy-2-methoxycarbonyl-allyl)-phenyl]-methyl}-acrylic acid methyl ester (127870-75-1)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; for 360h;

DOI:10.1055/s-1990-27016

Reference yield: 97.0%

2-{Hydroxy-[4-(1-hydroxy-2-methoxycarbonyl-allyl)-phenyl]-methyl}-acrylic acid methyl ester (127870-75-1) + acetyl chloride (75-36-5) → 2-{Acetoxy-[4-(1-acetoxy-2-methoxycarbonyl-allyl)-phenyl]-methyl}-acrylic acid methyl ester (127923-45-9)

Guidance literature:

With triethylamine;

DOI:10.1016/S0040-4039(01)93887-0

Reference yield: 88.0%

2-{Hydroxy-[4-(1-hydroxy-2-methoxycarbonyl-allyl)-phenyl]-methyl}-acrylic acid methyl ester (127870-75-1) + (1S,2S,5R)-6-(4-Methoxy-phenyl)-3-oxy-2-phenylselanylmethyl-3,6-diaza-bicyclo[3.2.0]hept-3-en-7-one → C54H54N4O12Se2

Guidance literature:

In ethylene glycol; at 20 ℃; for 1h; regioselective reaction; Ionic liquid; Green chemistry;

DOI:10.1016/j.tet.2016.12.004

upstream raw materials:

terephthalaldehyde,

acrylic acid methyl ester

Downstream raw materials:

C₁₆H₁₄O₈

1,4-di (3'-isopropylamino-2'-methoxycarbonylprop-1'-enyl) benzene

2-{Acetoxy-[4-(1-acetoxy-2-methoxycarbonyl-allyl)-phenyl]-methyl}-acrylic acid methyl ester