(+)-(S)-N-[(2S,3E)-2-phenyl-3-((S)-p-tolylsulfinyl)-3,5-hexadien-2-yl]-4-methylbenzenesulfinamide

Base Information

Chemical Name:(+)-(S)-N-[(2S,3E)-2-phenyl-3-((S)-p-tolylsulfinyl)-3,5-hexadien-2-yl]-4-methylbenzenesulfinamide
CAS No.:1350546-70-1
Molecular Formula:C₂₆H₂₇NO₂S₂
Molecular Weight:449.638
Hs Code.:

Synonyms:(+)-(S)-N-[(2S,3E)-2-phenyl-3-((S)-p-tolylsulfinyl)-3,5-hexadien-2-yl]-4-methylbenzenesulfinamide

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Chemical Property of (+)-(S)-N-[(2S,3E)-2-phenyl-3-((S)-p-tolylsulfinyl)-3,5-hexadien-2-yl]-4-methylbenzenesulfinamide

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Technology Process of (+)-(S)-N-[(2S,3E)-2-phenyl-3-((S)-p-tolylsulfinyl)-3,5-hexadien-2-yl]-4-methylbenzenesulfinamide

There total 1 articles about (+)-(S)-N-[(2S,3E)-2-phenyl-3-((S)-p-tolylsulfinyl)-3,5-hexadien-2-yl]-4-methylbenzenesulfinamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 951133-73-6
(R)-(1,3-Butadienyl)-p-tolyl-sulfoxid

: 866993-20-6
(S)-4-methyl-N-(1-phenylethylidene)benzenesulfinamide

: 1350546-70-1
(+)-(S)-N-[(2S,3E)-2-phenyl-3-((S)-p-tolylsulfinyl)-3,5-hexadien-2-yl]-4-methylbenzenesulfinamide

Guidance literature:: (R)-(1,3-Butadienyl)-p-tolyl-sulfoxid; With n-butyllithium; diisopropylamine; In tetrahydrofuran; at -78 ℃; for 0.3h;

(S)-4-methyl-N-(1-phenylethylidene)benzenesulfinamide; In tetrahydrofuran; at -78 ℃; for 0.166667h; optical yield given as %de; diastereoselective reaction;
DOI:10.1021/jo202144k

Reference yield: 81.0%

: 1350546-70-1
(+)-(S)-N-[(2S,3E)-2-phenyl-3-((S)-p-tolylsulfinyl)-3,5-hexadien-2-yl]-4-methylbenzenesulfinamide

: 1350546-81-4
(+)-(2S,3E)-2-phenyl-3-((S)-p-tolylsulfinyl)hexa-3,5-dien-2-amine

Guidance literature:: With phosphoric acid; In methanol; water; at 0 - 20 ℃; for 48h;
DOI:10.1021/jo202144k

Reference yield:

: 1350546-70-1
(+)-(S)-N-[(2S,3E)-2-phenyl-3-((S)-p-tolylsulfinyl)-3,5-hexadien-2-yl]-4-methylbenzenesulfinamide

: 1350546-90-5
(+)-N-[(2S,3E)-2-phenyl-3-((S)-p-tolylsulfinyl)-3,5-hexadien-2-yl]-4-methylbenzenesulfonamide

Guidance literature:: Multi-step reaction with 2 steps

1: phosphoric acid / methanol; water / 48 h / 0 - 20 °C

2: sodium carbonate / dichloromethane; water / 96 h / 20 °C

With phosphoric acid; sodium carbonate; In methanol; dichloromethane; water;
DOI:10.1021/jo202144k