(R)-linalyl oxide

Base Information

• Chemical Name: (R)-linalyl oxide
• CAS No.: 286428-24-8
• Molecular Formula: C₁₀H₁₈O₂
• Molecular Weight: 170.252
• Mol file: 286428-24-8.mol

Synonyms:(R)-linalyl oxide

Chemical Property of (R)-linalyl oxide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (R)-linalyl oxide

There total 4 articles about (R)-linalyl oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(S)-(+)-linalool (126-90-9) → 2,2,6-trimethyl-6-vinyltetrahydropyran-3-ol (10448-31-4,14009-71-3,14049-11-7,22628-11-1,24048-52-0,39028-58-5,41720-62-1) + (R)-linalyl oxide (286428-24-8,37267-80-4)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; trichloroacetic acid; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1.) CH₂Cl₂, 0 deg C, 2 h; 2.) ether, r.t., 12 h;

DOI:10.1016/0040-4020(95)00084-L

Reference yield:

(S)-(+)-linalool (126-90-9) → (R)-linalyl oxide (286428-24-8,37267-80-4) + (6R)-tetrahydro-2,2,6-trimethyl-6-vinyl-2H-pyran-3-one (13226-33-0)

Guidance literature:

With pyridine; chromium(VI) oxide; 3-chloro-benzenecarboperoxoic acid; trichloroacetic acid; Yield given. Multistep reaction. Yields of byproduct given; 1.) CH₂Cl₂, 0 deg C, 2 h; 2.) ether, r.t., 12 h; 3.) r.t., 2 h;

DOI:10.1016/0040-4020(95)00084-L

Reference yield:

acetic anhydride (108-24-7) + (S)-(+)-linalool (126-90-9) → (R)-linalyl oxide (286428-24-8,37267-80-4) + Acetic acid (R)-2,2,6-trimethyl-6-vinyl-tetrahydro-pyran-3-yl ester

Guidance literature:

With pyridine; 3-chloro-benzenecarboperoxoic acid; trichloroacetic acid; Yield given. Multistep reaction. Yields of byproduct given; 1.) CH₂Cl₂, 0 deg C, 2 h; 2.) ether, r.t., 12 h; 3.) r.t., 12 h;

DOI:10.1016/0040-4020(95)00084-L

upstream raw materials:

(S)-(+)-linalool

acetic anhydride

tert-butyldimethylsilyl chloride

Downstream raw materials:

(2R,5S)-5-(1-acetoxy-1-methylethyl)-2-ethenyl-2-methyl-perhydrofuran

(2R,5R)-5-(1-acetoxy-1-methylethyl)-2-ethenyl-2-methyl-perhydrofuran