tert-butyl{[(R)-1-{(2R,3R)-3-[(Z)-2-iodoethenyl]oxiran-2-yl}-propan-2-yl]oxy}diphenylsilane

Base Information

Chemical Name:tert-butyl{[(R)-1-{(2R,3R)-3-[(Z)-2-iodoethenyl]oxiran-2-yl}-propan-2-yl]oxy}diphenylsilane
CAS No.:1622322-45-5
Molecular Formula:C₂₃H₂₉IO₂Si
Molecular Weight:492.472
Hs Code.:

Synonyms:tert-butyl{[(R)-1-{(2R,3R)-3-[(Z)-2-iodoethenyl]oxiran-2-yl}-propan-2-yl]oxy}diphenylsilane

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Chemical Property of tert-butyl{[(R)-1-{(2R,3R)-3-[(Z)-2-iodoethenyl]oxiran-2-yl}-propan-2-yl]oxy}diphenylsilane

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Technology Process of tert-butyl{[(R)-1-{(2R,3R)-3-[(Z)-2-iodoethenyl]oxiran-2-yl}-propan-2-yl]oxy}diphenylsilane

There total 3 articles about tert-butyl{[(R)-1-{(2R,3R)-3-[(Z)-2-iodoethenyl]oxiran-2-yl}-propan-2-yl]oxy}diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 1622322-54-6
tert-butyl({(R)-1-[(2R,3R)-3-(iodoethynyl)oxiran-2-yl]propan-2-yl}oxy)diphenylsilane

: 1622322-45-5
tert-butyl{[(R)-1-{(2R,3R)-3-[(Z)-2-iodoethenyl]oxiran-2-yl}-propan-2-yl]oxy}diphenylsilane

Guidance literature:: With 2-nitrobenzenesulfonyl hydrazide; triethylamine; In tetrahydrofuran; isopropyl alcohol; at 25 ℃; for 40h; Inert atmosphere; Darkness;
DOI:10.1002/ejoc.201402205

Reference yield:

: 303044-46-4
(-)-(2R,3R,5R)-5-(tert-butyldiphenylsilyloxy)-2,3-(oxiranyl)-hexan-1-al

: 1622322-45-5
tert-butyl{[(R)-1-{(2R,3R)-3-[(Z)-2-iodoethenyl]oxiran-2-yl}-propan-2-yl]oxy}diphenylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: potassium carbonate / methanol / 3 h / 0 °C / Inert atmosphere

2: N-iodo-succinimide; silver nitrate / acetone / 1 h / 25 °C / Inert atmosphere; Darkness

3: 2-nitrobenzenesulfonyl hydrazide; triethylamine / tetrahydrofuran; isopropyl alcohol / 40 h / 25 °C / Inert atmosphere; Darkness

With N-iodo-succinimide; 2-nitrobenzenesulfonyl hydrazide; potassium carbonate; silver nitrate; triethylamine; In tetrahydrofuran; methanol; isopropyl alcohol; acetone;
DOI:10.1002/ejoc.201402205

Reference yield:

: 1622322-52-4
tert-butyl({(R)-1-[(2R,3R)-3-ethynyloxiran-2-yl]propan-2-yl}oxy)-diphenylsilane

: 1622322-45-5
tert-butyl{[(R)-1-{(2R,3R)-3-[(Z)-2-iodoethenyl]oxiran-2-yl}-propan-2-yl]oxy}diphenylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: N-iodo-succinimide; silver nitrate / acetone / 1 h / 25 °C / Inert atmosphere; Darkness

2: 2-nitrobenzenesulfonyl hydrazide; triethylamine / tetrahydrofuran; isopropyl alcohol / 40 h / 25 °C / Inert atmosphere; Darkness

With N-iodo-succinimide; 2-nitrobenzenesulfonyl hydrazide; silver nitrate; triethylamine; In tetrahydrofuran; isopropyl alcohol; acetone;
DOI:10.1002/ejoc.201402205